Mononuclear Iron Compounds: Ferrocenes

Butler, Ian R.; Thomas, Dafydd A.

doi:10.1016/b0-08-045047-4/00084-4

Cited by 7 publications

(5 citation statements)

References 508 publications

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“…Ever since the discovery of ferrocene in 1951, this molecule has inspired researchers from many fields of basic and applied chemistry. This multifaceted chemistry has been highlighted on many occasions, and very recently a whole volume of Organometallics has been dedicated to its “Beauty and Function” . While most of the “applied research” was focused on the use of ferrocene derivatives as ligands for catalyst design, and more recently in bioorganometallic chemistry and medicinal chemistry, the possibility of inducing high thermal and oxidative stability by proper introduction of substituents has attracted material chemists already over 40 years ago.…”

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confidence: 99%

Synthesis and Characterization of 1,2,3,4,5-Pentafluoroferrocene

et al. 2014

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confidence: 99%

Synthesis and Characterization of 1,2,3,4,5-Pentafluoroferrocene

et al. 2014

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“…Ferrocene, recognized as the progenitor of organometallic chemistry, has given rise to an enormous number of ferrocenecontaining ligands, molecules, and materials since its discovery in 1951 (Kealy and Pauson, 1951;Butler and Thomas, 2007;Štěpnička, 2008;Dai and Hou, 2010;Phillips, 2011;Ding et al, 2019). Synthetic flexibility, well-defined redox properties, and fast reaction kinetics make them very promising for RFBs.…”

Section: Coordination Compounds and Organometallic Complexesmentioning

confidence: 99%

Organic Electroactive Molecule-Based Electrolytes for Redox Flow Batteries: Status and Challenges of Molecular Design

et al. 2020

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This is a critical review of the advances in the molecular design of organic electroactive molecules, which are the key components for redox flow batteries (RFBs). As a large-scale energy storage system with great potential, the redox flow battery has been attracting increasing attention in the last few decades. The redox molecules, which bridge the interconversion between chemical energy and electric energy for RFBs, have generated wide interest in many fields such as energy storage, functional materials, and synthetic chemistry. The most widely used electroactive molecules are inorganic metal ions, most of which are scarce and expensive, hindering the broad deployment of RFBs. Thus, there is an urgent motivation to exploit novel cost-effective electroactive molecules for the commercialization of RFBs. RFBs based on organic electroactive molecules such as quinones and nitroxide radical derivatives have been studied and have been a hot topic of research due to their inherent merits in the last decade. However, few comprehensive summaries regarding the molecular design of organic electroactive molecules have been published. Herein, the latest progress and challenges of organic electroactive molecules in both non-aqueous and aqueous RFBs are reviewed, and future perspectives are put forward for further developments of RFBs as well as other electrochemical energy storage systems.

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“…[13,17] Moreover, chalcogenide complexes are the best alternative of phosphine based complexes due to the high electron donating properties of chalcogens as depicted by the catalytic potential of these in efficient CÀ C and CÀ N bond formation reactions. [13,16,17] Owing to the importance and properties of ferrocene [18] in various domains [19] including the electrochemistry, [20] pharmaceuticals, [21] agrochemical, [22] bio-sensing, [23] solvatochromism [24] and other, [25] increasing the library of ferrocenated molecules is always encouraged. Ferrocene substituted β-azoles cinnamaldehydes and acrylonitriles have important role in medicinal chemistry, cancer therapy and proliferative.…”

Section: Introductionmentioning

confidence: 99%

“…Owing to the importance and properties of ferrocene [18] in various domains [19] including the electrochemistry, [20] pharmaceuticals, [21] agrochemical, [22] bio‐sensing, [23] solvatochromism [24] and other, [25] increasing the library of ferrocenated molecules is always encouraged. Ferrocene substituted β ‐azoles cinnamaldehydes and acrylonitriles have important role in medicinal chemistry, cancer therapy and proliferative [26–30] …”

Section: Introductionmentioning

confidence: 99%

Novel Ferrocenyl‐azole Derivatives: Synthesis, DFT Calculation and Unlocking the Anticancer Potential

Tomar,

Kumar,

Sharma

et al. 2024

Eur J Org Chem

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Herein, a series of novel ferrocenyl/phenyl/thiophenyl‐azoles was disclosed by vinylic amination of ferrocenyl/phenyl/thiophenyl substituted β‐chloro cinnamaldehydes and acrylonitriles. A highly economical and robust chalcogen‐stabilized iron selenide carbonyl cluster Fe3Se2(CO)9 worked as an efficient catalyst under aerobic conditions. The amination of ferrocenyl/phenyl/thiophenyl substituted β‐chloro‐vinylic Csp2‐Cl with azole derivatives was fully established and fabrication of the Csp2‐N bond was completely supported by various spectral analysis. Moreover, wide range of substrates with functionally different azoles were investigated for the present reaction and good to excellent transformation was recorded. Some of the selected ferrocenated azole derivatives were screened for anti‐cancer activity against the prostate cancer cells (PC‐3) and found to be highly active at low concentration of 5.77µM with IC50 value. Furthermore, HOMO and LUMO levels and energy gap of some selected compounds were calculated by the density functional theory (DFT).

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Mononuclear Iron Compounds: Ferrocenes

Cited by 7 publications

References 508 publications

Synthesis and Characterization of 1,2,3,4,5-Pentafluoroferrocene

Synthesis and Characterization of 1,2,3,4,5-Pentafluoroferrocene

Organic Electroactive Molecule-Based Electrolytes for Redox Flow Batteries: Status and Challenges of Molecular Design

Novel Ferrocenyl‐azole Derivatives: Synthesis, DFT Calculation and Unlocking the Anticancer Potential

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