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iii Executive SummaryThe purpose of this research is to develop and maintain numerical groundwater flow and transport models that can be used to refine the conceptual site model for groundwater beneath the 300 Area, and to assist in evaluating alternative remediation technologies focused on the 300 Area uranium plume. Groundwater flow rates and directions in the 300 Area are very dynamic because of the high hydraulic conductivities, along with the large daily, weekly, and seasonal fluctuations in the Columbia River stage. Quantifying the dynamics of groundwater flow and transport in the 300 Area aquifer will help understand the significant seasonal variability of uranium plume concentrations seen in biannual groundwater monitoring, and will help evaluate remediation options. Groundwater flow rates are very high in the upper portion of the 300 Area unconfined aquifer (within the Hanford formation), with velocities up to 10 to 15 m/d (35 to 50 ft/d) based on a tracer test and limited plume-migration data. Variability in the groundwater-flow directions is apparent from analysis of hourly and subhourly automated water-level measurements from monitoring networks established in the 300 Area. Generalized flow directions in the area between the north and south process ponds are toward the east to south, with the directions changing toward the south and west during periods of increases in the river stage (daily and seasonal).High-resolution water level and river stage data were required to simulate the dynamics of the 300 Area aquifer. Two scales of groundwater flow and transport models were developed based on the availability of high-resolution water-level monitoring data. A larger-domain model was developed that includes the 300 Area and extends north and south using data from the early 1990s water-level monitoring network. A smaller domain model was developed for a portion of the large scale model domain in the north of the 300 Area that used water-level data from another smaller monitoring well network that was established in 2004. These models focus on the highly permeable upper portion of the unconfined aquifer within the Hanford formation that has hydraulic conductivity values 2 to 3 orders of magnitude higher than the underlying Ringold Formation aquifers. These models simulate saturated and unsaturated groundwater flow and transport with the STOMP code, which was developed at Pacific Northwest National Laboratory. 1The hydrostratigraphy, topography, and bathymetry for the three-dimensional models used a consistent framework using EarthVision software.The model domains include the lower portion of the vadose zone to encompass the range of river stage and water- The hydrostratigraphic units were determined from previously published interpretations of the 300 Area, along with data from additional wells installed since those studies. A reanalysis of some of the older geologic unit picks from well logs in the area, along with using geophysical logs, was conducted based on the detailed knowledge gained from the 300 ...
iii Executive SummaryThe purpose of this research is to develop and maintain numerical groundwater flow and transport models that can be used to refine the conceptual site model for groundwater beneath the 300 Area, and to assist in evaluating alternative remediation technologies focused on the 300 Area uranium plume. Groundwater flow rates and directions in the 300 Area are very dynamic because of the high hydraulic conductivities, along with the large daily, weekly, and seasonal fluctuations in the Columbia River stage. Quantifying the dynamics of groundwater flow and transport in the 300 Area aquifer will help understand the significant seasonal variability of uranium plume concentrations seen in biannual groundwater monitoring, and will help evaluate remediation options. Groundwater flow rates are very high in the upper portion of the 300 Area unconfined aquifer (within the Hanford formation), with velocities up to 10 to 15 m/d (35 to 50 ft/d) based on a tracer test and limited plume-migration data. Variability in the groundwater-flow directions is apparent from analysis of hourly and subhourly automated water-level measurements from monitoring networks established in the 300 Area. Generalized flow directions in the area between the north and south process ponds are toward the east to south, with the directions changing toward the south and west during periods of increases in the river stage (daily and seasonal).High-resolution water level and river stage data were required to simulate the dynamics of the 300 Area aquifer. Two scales of groundwater flow and transport models were developed based on the availability of high-resolution water-level monitoring data. A larger-domain model was developed that includes the 300 Area and extends north and south using data from the early 1990s water-level monitoring network. A smaller domain model was developed for a portion of the large scale model domain in the north of the 300 Area that used water-level data from another smaller monitoring well network that was established in 2004. These models focus on the highly permeable upper portion of the unconfined aquifer within the Hanford formation that has hydraulic conductivity values 2 to 3 orders of magnitude higher than the underlying Ringold Formation aquifers. These models simulate saturated and unsaturated groundwater flow and transport with the STOMP code, which was developed at Pacific Northwest National Laboratory. 1The hydrostratigraphy, topography, and bathymetry for the three-dimensional models used a consistent framework using EarthVision software.The model domains include the lower portion of the vadose zone to encompass the range of river stage and water- The hydrostratigraphic units were determined from previously published interpretations of the 300 Area, along with data from additional wells installed since those studies. A reanalysis of some of the older geologic unit picks from well logs in the area, along with using geophysical logs, was conducted based on the detailed knowledge gained from the 300 ...
This report represents a synthesis and integration of basic and applied research into a system-scale model of the Hanford 300 Area groundwater uranium plume, supported by the U.S. Department of Energy (DOE) Richland Operations Office (RL). The report integrates research findings and data from DOE Office of Science (SC), Office of Environmental Management (EM), and DOE-RL projects, and from the site remediation and closure contractor, Washington Closure Hanford, LLC. The threedimensional, system-scale model addresses water flow and reactive transport of uranium for the coupled vadose zone, unconfined aquifer, and Columbia River shoreline of the Hanford 300 Area. The system-scale model of the 300 Area was developed to be a decision-support tool to evaluate processes of the total system affecting the groundwater uranium plume. The model can also be used to address "what if" questions regarding different remediation endpoints, and to assist in design and evaluation of field remediation efforts. For example, the proposed cleanup plan for the Hanford 300 Area includes removal, treatment, and disposal of contaminated sediments from known waste sites, enhanced attenuation of uranium hot spots in the vadose and periodically rewetted zone, and continued monitoring of groundwater with institutional controls. Illustrative simulations of polyphosphate infiltration were performed to demonstrate the ability of the system-scale model to address these types of questions. The use of this model in conjunction with continued field monitoring is expected to provide a rigorous basis for developing operational strategies for field remediation and for defining defensible remediation endpoints. The system-scale flow and reactive transport model of the 300 Area subsurface was implemented using the simulator eSTOMP ("e" for extreme scale), developed recently by Pacific Northwest National Laboratory (PNNL) under the laboratory-directed research and development program's Extreme-Scale Computing Initiative. This is a parallel version of the STOMP (Subsurface Transport Over Multiple Phases) simulator that was developed specifically to allow for simulation with faster run times and/or for larger-scale subsurface flow and reactive transport problems. All model simulations with eSTOMP were performed on Olympus, a high-performance computing cluster supported by PNNL's institutional computing program. Data from laboratory and field experiments performed for the Integrated Field Research Challenge (IFRC) project, supported by DOE-SC, and from other DOE-EM and DOE-RL projects, were used for model development and testing. A column experiment performed on an intact, uranium-contaminated core sample collected from the IFRC site was used as a small-scale validation test for a uranium surface complexation reaction network implemented with eSTOMP. Experimental data from this and other laboratory column experiments with 300 Area sediments were used to develop an alternative reaction network that also accounts for reactions associated with polyphosphate amen...
these estimates is caused by the need to make certain assumptions, such as the thickness of the contaminated layer. However, for the period evaluated, the trends in parameters suggest a relatively constant level of contamination, but with some variability. At the 618-11 sub-region, monitoring results since 1999 show decreasing tritium concentrations at wells closest to the source and variable concentrations at wells along the downgradient migration pathway. This plume has not reached the Energy Northwest water supply wells, nor the Columbia River. At the 316-4/618-10 sub-region, COPC are currently at levels below the drinking water standards, except for very recent samples from two wells near the 316-4 cribs excavation site that show concentrations near the 30-ug/L standard for uranium. A revised strategy for categorizing waste constituents in groundwater as a COC or COPC, along with the implications for remedial actions and regulatory decisions, is proposed. As a result, the lists developed during the remedial investigation have been shortened, primarily because of improving conditions and lack of evidence suggesting unacceptable risk. Conceptual Site Model for 300 Area Uranium. The 300 Area uranium plume can be characterized as persistent, i.e., the area and concentrations have remained similar to early 1990 conditions. There has been variability in spatial and temporal distribution patterns, primarily as a consequence of (a) cessation of liquid waste disposal to the ground, (b) large-scale source excavation activities, (c) unusually high and prolonged water table conditions during 1996 and 1997, and (d) seasonality because of river-stage fluctuations. During the most recent years, the plume appears to be relatively stable, with evidence showing gradual downgradient migration to the Columbia River. The highest concentrations observed currently are along the shoreline, and probably reflect the last significant input from beneath former major waste sites, such as the 316-5 process trenches. Uranium is lost from the plume via discharge to the river and groundwater withdrawal at a water supply well. Some amount of re-supply to the plume is believed to occur as a consequence of long-term release of uranium that has been sequestered on vadose zone and aquifer solids. The mobility of uranium and controls on dissolved concentrations are influenced by the geochemistry of the original waste effluent, the receiving sediment, and pore fluids, all of which vary in the 300 Area environment. The compositional and spatial variability leads to complexity in computer models designed for predicting plume behavior. The heterogeneity in conditions also drives the need for more field data on the locations, inventory, and geochemical characteristics of uranium in potential source zones. Conceptual Site Model for 618-11 Tritium. The tritium plume associated with the 618-11 sub-region has apparently been created by episodic release of tritium gas from irradiated materials in the burial ground. The gas interacts with moisture in the vad...
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