Modified Markó’s aerobic oxidation of alcohols under atmospheric pressure with air or molecular oxygen at room temperature

Aerobic Copper-Catalyzed Organic Reactions

“…These reports include: reviews (Section I), 1149,1150,1151,1152 oxygenation of unactivated benzylic substrates (Section IIA.2), 1153,1154,1155 alkane oxidation (Section II.B), 1156,1157,1158 epoxidation of alkenes (Section II.C.2), 1159 oxidation difunctionalization of alkenes (Section II.C.3), 1160,1161,1162,1163,1164 cross coupling with alkynes (Section II.D.3), 1165 oxidation difunctionalization of alkynes (Section II.D.4), 1166,1167,1168 arene hydroxylation (Section II.E.1), 1169 reactions involving nucleophilic arenes (Section II.E.2), 1170 direction insertion of arenes (Section II.E.3), 1171,1172,1173,1174,1175 functionalization of acidic arene positionos (Section II.E.4), 1176,1177,1178 coupling of carbanion equivalents with boronic acids (Section III.C), 1179,1180,1181,1182,1183,1184,1185 alcohol oxidation (Section IV.A.1),1186,1187,1188,1189,1190,1191,1192,1193,1194,1195,1196,1197,1198,1199 tandem reaction with alcohol oxidation (Section IV.D), 1200,1201,1202,1203,1204,1205,1206,1207,1208 oxidation of aldehydes to amides (Section V.A), 1209 enolate oxiation without cleavage (Section V.C), 1210,1211 oxidative coupling of enolates (Section V.C.1), 1212 α-oxygenation of carboxylic acids (Section V.E), 1213 reaction of hydrazones (Section V.G), 1214 oxidation of hydrazones with cyclization (Section V.G), 12151216 reactions of enamines (Section VI.A), 1217,…”

Chemo-enzymatic pathways toward pinene-based renewable materials

“…The SobMA was synthesized via a conventional chemical approach starting from commercially available sobrerol, using methacryloyl chloride and triethyl amine in DMF. DMF was not a preferred solvent but despite previous reports, 48,49 sobrerol proved difficult to dissolve. Purification via medium pressure liquid chromatography (MPLC) yielded the liquid SobMA monomer in 66% yield.…”

Cu-Catalyzed Aerobic Oxidation of Di-tert-butyl Hydrazodicarboxylate to Di-tert-butyl Azodicarboxylate and Its Application on Dehydrogenation of 1,2,3,4-Tetrahydroquinolines under Mild Conditions

“…In 1996, Markó and co-workers reported that the combination of Cu, 1,10-phenanthroline, and DBAD could catalyze the aerobic oxidation of alcohol to aldehyde . They proposed that the Cu/DBAD complex was generated by the hydrogen abstraction of the hydrazino-copper species.…”