However interrupted voltage application had a negative impact on dewatering in this study, probably because the off-times were too long.Other factors affecting dewatering performance were associated to the original sludge characteristics and sludge conditioning. Anaerobic digestion of the sludge with high pH buffering capacity, polymer addition and freeze/thaw conditioning had a positive impact on dewatering. The impact of pH on electro-dewatering was related to the surface charge of the particles measured as zeta-potential.One of the differences between electro-dewatering and mechanical dewatering technologies is that electro-dewatering actively removes ionic compounds from the sludge. In this study, dissolution and migration of organic compounds (such as shortchain fatty acids), macro metals (Na, K, Ca, Mg, Fe) and trace metals (Ni, Mn, Zn, Cr) was investigated. The migration of the metals depended on the fractionation and electrical field strength. These compounds may have both negative and positive impacts on the reuse and recycling of the sludge and removed water.Based on the experimental results of this study, electro-dewatering process can be optimized in terms of dewatering time, desired DS content, power consumption and chemical usage.