This work reports on the Yb 3 þ ion addition effect on the near infrared emission and infrared-to-visible up conversion from planar waveguides based on Er 3 þ-Yb 3 þ co-doped Nb 2 O 5 nanocrystals embedded in SiO 2-based nanocomposite prepared by a sol-gel process with controlled crystallization in situ. Planar waveguides and xerogels containing Si/Nb molar ratio of 90:10 up to 50:50 were prepared. Spherical-like orthorhombic or monoclinic Nb 2 O 5 nanocrystals were grown in the amorphous SiO 2-based host depending on the niobium content and annealing temperature, resulting in transparent glass ceramics. Crystallization process was intensely affected by rare earth content increase. Enhancement and broadening of the NIR emission has been achieved depending on the rare earth content, niobium content and annealing temperature. Effective Yb 3 þ-Er 3 þ energy transfer and a high-intensity broad band emission in the near infrared region assigned to the Er 3 þ ions 4 I 13/2-4 I 15/2 transition, and longer 4 I 13/2 lifetimes were observed for samples containing orthorhombic Nb 2 O 5 nanocrystals. Intense green and red emissions were registered for all Er 3 þ-Yb 3 þ co-doped waveguides under 980 nm excitation, assigned to 2 H 11/2-4 I 15/2 (525 nm), 4 S 3/2-4 I 15/2 (545nm) and 4 F 9/2-4 I 15/2 (670 nm) transitions, respectively. Different relative green and red intensities emissions were observed, depending upon niobium oxide content and the laser power. Upconversion dynamics were determined by the photons number, evidencing that ESA or ETU mechanisms are probably occurring. The 1931 CIE chromaticity diagrams indicated interesting color tunability based on the waveguides composition and pump power. The nanocomposite waveguides are promising materials for photonic applications as optical amplifiers and WDM devices operating in the S, C, and L telecommunication bands; and as upconverter materials for visible upconversion lasers, biomedical applications, energy conversion for solar cells and others.