“…The off‐gas parameters of the BOF process are high temperatures (1,400–1,600 °C), high off‐gas volumes (∼60–80 m 3 (STP)/t crude steel) with a high amount of pure iron and iron‐oxide dust particles in a micrometer range (∼ 15–20 kg/t crude steel), so‐called “brown smoke”, and gas compositions containing 60–80 vol.‐% {CO} and 5–20 vol.‐% {CO 2 } 4, 5, 21. The evaluation of available optical measurement methods shows, that the application of passive FTIR spectroscopy is advantageous for the measurement of hot gases, because no additional external signal source is required; instead the internal heat of the gas is used as radiation source.…”