In atmospheric radio frequency discharges at 13.56 MHz, with the electrode gap reduced, the sheath region eventually occupies a main portion of the electrode spacing and the bulk plasma region is significantly compressed. The computational results in this letter based on a one-dimensional fluid model show that by increasing the excitation frequency over 13.56 MHz, the traditional glow-plasma structure could gradually recover even at very small sizes with a well defined quasineutral plasma region, and the electron density is improved but the electric fields in sheath region are reduced. This study indicates that the excitation frequency can be used to modulate the discharge structure and then tailor the plasma-surface interaction in atmospheric microplasmas.Atmospheric microplasmas have commanded much attention in recent years due to the considerable scientific depth and potential applications. 1-4 For atmospheric capacitively radio-frequency (rf) discharges, when the electrode gaps are confined to submillimeter dimensions, the generated microplasmas show many unique properties compared to the large-scale atmospheric plasmas, 3 such as the high energetic electrons, 5 different discharge structures, 6,7 and nonequilibrium characters. 8 The experimental 6 and computational studies 5,7 have demonstrated that in atmospheric rf discharges at 13.56 MHz, with the electrode gap reduced, the traditional glow-plasma (GP) structure will eventually transit to a new sheath-dominated-plasma (SDP) structure, where the sheath region occupies a large portion of the electrode gap and almost no distinct bulk plasma region develops. In a SDP structure, three electron groups with different electron temperatures have been revealed by the Particle-In-Cell (PIC) simulation and the high energetic electrons present a new way to interact with the electrodes or the given surfaces, moreover these electrons maybe contribute to the reactivity of atmospheric microplasmas. 5 The discharge modes in rf microplasmas have been discussed but still need to be further clarified by experiments and simulations. 5-7 Increasing frequency is widely accepted as a way to enhance the discharge stability and reduce the electron temperature at a constant power density. 10-12 Nevertheless, the frequency effects on the structure transition in atmospheric rf discharges are largely unexplored. Although the microplasmas in SDP regime show many advantages and the GP structure with quasineutral plasmas may still be very useful in many applications at very small sizes. The experimental diagnosis of atmospheric microplasmas, however, is facing many new challenges due to the small dimension and high gas pressure, 3,4 and numerical simulations provide a valuable alternative for investigating the properties of microplasmas. 2In this letter a one-dimensional fluid model is explored to study the transition of discharge structures in capacitively rf discharges at atmospheric pressure. 11,12 Briefly, the continuity equations with the drift-diffusion approximation are used to des...