A hybrid model was used to simulate a dc argon micro glow-discharge at atmospheric pressure. The simulations were carried out for a pin-plate electrode configuration with inter-electrode gap spacing of 200 µm together with an external circuit. The predicted voltage-current characteristics and current density profiles identify the discharge to be a normal glow-discharge. The neutral gas temperature predictions indicate that the discharge forms a non-thermal, non-equilibrium plasma. Experimental studies were conducted to validate the numerical model. Predictions from the numerical model compare favourably with the experimental measurements.
When a liquid and its vapor contact a smooth, homogeneous surface, Gibbsian thermodynamics indicates that the contact angle depends on the pressure at the three-phase line of an isothermal system. When a recently proposed adsorption isotherm for a solid-vapor interface is combined with the equilibrium conditions and the system is assumed to be in a cylinder where the liquid-vapor interface can be approximated as spherical, the contact-angle-pressure relation can be made explicit. It indicates that a range of contact angles can be observed on a smooth homogeneous surface by changing the pressure at the three-phase line, but it also indicates that the adsorption at the solid-liquid interface is negative, and leads to the prediction that the contact angle increases with pressure. The predicted dependence of the contact angle on pressure is investigated experimentally in a system that has an independent mechanism for determining when thermodynamic equilibrium is reached. The predictions are in agreement with the measurements. The results provide a possible explanation for contact angle hysteresis.
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