Abstract:Effect of illumination on mobility has been studied from the photocurrent decay characteristics of thermally evaporated CdSe thin films deposited on suitably cleaned glass substrate held at elevated substrate temperatures. The study indicates that the mobilities of the carriers of different trap levels are activated due to the energy of incident illumination, which results in the existence of two distinct trap levels. In each trap depth the energy of the trap increases linearly. It infers that there is a linea… Show more
“…Kangkan et al have reported that the increase in PC occurs due to two contributors viz. one from the resultant increase in the photogenerated charge carriers and other due to the increase in the effective mobility which is a function of temperature [72]. A high value of electron mobility for sample R2 also implies that the sample R2 is pure and structurally more perfect than sample R1.…”
“…Kangkan et al have reported that the increase in PC occurs due to two contributors viz. one from the resultant increase in the photogenerated charge carriers and other due to the increase in the effective mobility which is a function of temperature [72]. A high value of electron mobility for sample R2 also implies that the sample R2 is pure and structurally more perfect than sample R1.…”
“…From this figure it is observed that there exist 2 different slops in the plots, which indicates the existence of 2 distinct trap levels, E1 and E2, at the considered room temperature. The trap depths are not single valued and there is a quasi-continuous distribution of trap levels below the conduction band [21,34]. It may be noted that photocurrent in these thin films is found to obey a sub-linear relation with the intensity of illumination (Figure 5(a)) which may be explained on the basic of defect controlled photoconductivity mechanism.…”
Section: Growth and Decay Of Photocurrentmentioning
confidence: 96%
“…Nanocrystalline thin films of CdSe have been prepared using different methods [9][10][11][12][13][14][15][16], out of which CBD technique is mainly used because of its simplicity, effectiveness and variability [17][18][19]. Although wide range of works on the synthesis and characterization of nanocrystalline thin films of CdSe have already been reported [9][10][11][12][13][14][15][16][17][18][19], but only few works on the photoelectronic properties specifically based on the wavelength and the intensity of incident illumination have been found in the available literatures [20,21]. Reported works have basically considered the complete range of visible light spectrum i.e.…”
Photoelectronic properties of nanocrystalline CdSethin films prepared by chemical bath deposition (CBD) technique at room temperature are studied taking its molar concentration as a function. Structural analysis of the deposited thin films shows that change of molarity brings a variation in the crystalline sizes of the thin films. Such thin films show suitable photoelectronic properties for the construction of different optoelectronic devices. The photocurrents are observed to be significantly defect controlled in the visible range of wavelengths. The transport mechanism for the thin films is generally a doubly activated process and the photocurrent decay characteristics curves are found to exhibit 2 different decay times which actually correspond to 2 distinct trap levels.
HIGHLIGHTS
The photoelectronic properties of nanocrystalline CdSe thin films deposited by CBD method are studied
From the XRD of the films diffraction peaks may be indexed to diffraction basically from the (111) plane of zincblende structure
The optical band gap may be varied with the molarity of the solution used for deposition
Photoelectronic properties are dependent of the intensity of different monochromatic illuminations
Photocurrents for the films are basically controlled by the grain boundary defects
Growth and decay of photocurrent are effectively governed by different kind of traps
GRAPHICAL ABSTRACT
“…Many studies of traps in poly-CdSe films [7][8][9][10] have revealed that there are two kinds of bulk trap states relevant for poly-TFTs electrical characteristics. In case of N-type poly-CdSe, they refer as shallow and deep traps with energy densities peaking at around 0.13 eV and 0.4 eV bellow the conduction band, respectively [7][8][9][10].…”
Section: Tdds In Poly-cdse Thin Filmmentioning
confidence: 99%
“…In case of N-type poly-CdSe, they refer as shallow and deep traps with energy densities peaking at around 0.13 eV and 0.4 eV bellow the conduction band, respectively [7][8][9][10]. It has been recently shown [10] that the experimentally observed gradual transition from the subtreshold to the postthreshold regime of CdSe poly-TFTs is due to effect of the trapping-detrapping process at shallow trap states, whereas the subtreshold slope has a strong dependence on TDD of the deeper traps.…”
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