The variation of optical properties of Ba 0.75 Al 11 O 17.25 :Mn 2+ with the increase of Mn 2+ concentration was investigated under vacuum ultraviolet excitation. A redshift of emission peak and a decrease of decay time with Mn 2+ concentration were observed. After analysis by a method of Pade approximations developed by Yokota and Tanimoto, these phenomena are attributed to the formation of Mn 2+ paired centers.Mn 2+ -doped BaAl 12 O 19 has been regarded as a candidate in place of Zn 2 SiO 4 :Mn 2+ as the green-emitting component in plasma display panels ͑PDPs͒ and Hg-free lamps due to its high color purity, luminescence efficiency, and stability under severe display operating conditions. 1 However, the long decay time ͑Ͼ5 ms͒ caused by the double spin and parity-forbidden 4 T 1 → 6 A 1 transition of Mn 2+ hinders its application in displays. In Zn 2 SiO 4 :Mn 2+ , the decay time becomes shorter with the increase of the concentration of Mn 2+ along with the emission peak shift to the long wavelength side. 2 These phenomena have also been found in other Mn 2+ activated phosphors and ascribed to the formation of Mn 2+ -Mn 2+ pair centers which exhibit different spectroscopic characteristics, especially much shorter decay time than those of isolated Mn 2+ . 2-7 But the reports on the variation of optical properties of BaAl 12 O 19 :Mn 2+ with the change of Mn 2+ concentration is rare. The fact that BaAl 12 O 19 :Mn 2+ does not fluoresce under UV excitation may be one of the reasons. Until now, only Sohn et al. reported the decrease of decay time of BaAl 12 O 19 :Mn 2+ with the increase of Mn 2+ concentration, but they considered that no Mn 2+ -Mn 2+ pairs exist because emission peak shift was not observed by them. 1 However, we do find peak movement in other authors' report though they did not mention it. 8 Thus detail investigation is necessary to clarify this contradiction.The main purpose of the present investigation is to make clear the nature of the concentration effect on the optical properties, especially the decay behavior of BaAl 12 O 19 :Mn 2+ . It is well known that BaAl 12 O 19 consists of 0.82 BaO·6 Al 2 O 3 ͑Ba 0.75 Al 11 O 17.25 , phase I͒ and 1.32 BaO·6 Al 2 O 3 ͑phase II͒ 9 and the latter's structure is not clear yet. Thus, Ba 0.75 Al 11−x O 17.25 :x Mn 2+ is prepared in this work to make it feasible to discuss experimental results in detail. Emission spectra and decay curves were measured and utilized to analyze the spectroscopic properties of Ba 0.75 Al 11 O 17.25 with different Mn 2+ doping concentrations.
ExperimentalBa 0.75 Al 11− xO 17.25 :x Mn 2+ ͑0.001 ഛ x ഛ 0.8͒ were prepared with the solid-state reaction method. Stoichiometric amounts of BaCO 3 ͑99%͒, Al 2 O 3 ͑99.99%͒, and MnCO 3 ͑99%͒ were mixed and ground thoroughly. Then, the samples were annealed at 1500°C for 4 h under a flow of 5% H 2 /95% N 2 , followed by milling. The phases of the samples were examined by a Rigaku D/max-2400 X-ray diffractometer ͑XRD͒ with Ni-filtered Cu K␣ radiation. The photoluminescence properties were measu...