“…Spectral data, both wavenumber ( v ) and absorbance ( a ), were smoothed using Average-Based Spectral Filter (ABSF) with a data window of 3 and 20 cycles; later, self-scaling of data of absorbance was carried out and, finally, self-scaled data were used as in-put data for the deconvolution function permitting to obtain the corresponding FEDS spectra. Details of this procedure have been previously published [34] , [35] , [36] , [37] . In order to define one standard criterion to identify the occurrence of shifts, the following aspects were taken in considering: (i) small differences are usual in IR spectra, (ii) spectral resolution is defined by two consecutive wavenumbers, being in our case, Δ v = 1.93 cm −1 , and (iii) by FEDS a variability around Δ v cm −1 is unavoidably produced due to differentiation procedure.…”