New dielectric ceramics are prepared by the conventional solid-state ceramic route. Effects of LZB glass on sintering, phase purity, microstructure, and dielectric properties of Li 2 ZnTi 3 O 8 ceramics have been investigated. Adding LZB lowers sintering temperature from 1050°C to 875°C, and does not induce much degradation of dielectric properties. The 1.0 wt% LZB glass-added ceramic has better properties of e r = 23.9, Q 9 f = 31,608 GHz, τ f = À14.3 ppm/°C. Additions of TiO 2 markedly improve microwave properties. Typically, the Li 2 ZnTi 3 O 8 + 1 wt%LZB + 3.5 wt%TiO 2 sintered at 900°C shows e r = 26.1, Q 9 f = 45,168 GHz, τ f = À4.1 ppm/°C. Compatibility with Ag electrode indicates that this material may be applied to LTCC devices.