Microwave-assisted rapid synthesis of titanium phosphate free phosphorus doped Ti₃C₂ MXene with boosted pseudocapacitance

Abstract

Phosphorous (P) doping is well-known for the variety of energy materials with improved energy storage performances, however, it remains rarely explored for Ti3C2 MXene. The primary bottleneck of developing P...

Defect engineering of two-dimensional materials for advanced energy conversion and storage

“…105 As analyzed by density functional theory (DFT) calculations, Enyashin et al reported Re doping could promote the transition of the 2H phase and finally thermodynamically stabilize the 1T-MoS 2 nanosheets. 106 Moreover, some non-metal elements like O, 107 P, 108 and S 109 are usually doped into highly conductive MXene nanosheets via substituting the lattice C or N atoms. Recently, Peng and co-workers synthesized the single-atomic Ru doped Mo 2 CT x MXene nanosheets by reaction in solution to improve the catalytic activity (Fig.…”

Template-free synthesis of mesoporous and amorphous transition metal phosphate materials

“…Typically, TMPs are synthesized by precipitation from solution, hydrothermal methods, molten salt, microwave, or mechanochemical syntheses [20][21][22][23][24][25] . Thereby, highly crystalline and/or amorphous bulk TMPs can be obtained.…”

“…[16][17][18][19] Typically, TMPs are synthesized by precipitation from solution, hydrothermal methods, molten salt, microwave, or mechanochemical syntheses. [20][21][22][23][24][25] Thereby, highly crystalline and/or amorphous bulk TMPs can be obtained. In particular, the amorphous state is often desired, because the absence of long-range ordering in TMPs enhances their reaction kinetics compared to the crystalline equivalents.…”

Template-free synthesis of mesoporous and amorphous transition metal phosphate materials

“…Typically, TMPs are synthesized by precipitation from solution, hydrothermal methods, molten salt, microwave, or mechanochemical syntheses [15][16][17][18][19][20] Thereby, highly crystalline and/or amorphous bulk TMPs can be obtained. In particular, the amorphous state is often desired, because the absence of long-range ordering in amorphous TMPs enhances their reaction kinetics compared to the crystalline equivalents 21,22 .…”