2010
DOI: 10.1088/0022-3727/43/24/245003
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Microwave absorption properties of FeNi3 submicrometre spheres and SiO2@FeNi3 core–shell structures

Abstract: Nearly monodispersed FeNi3 submicrometre spheres with an average diameter of 220 nm were synthesized by a simple low temperature reduction method. SiO2@FeNi3 core–shell structured submicrometre spheres with 25 nm thick SiO2 shell were then fabricated by a sol–gel process. A significant enhancement of electromagnetic absorption (EMA) performance was achieved by the silica coating over the 2–18 GHz. The reflection loss (RL) exceeding −20 dB of the composite was obtained over 6.7–15.1 GHz by choosing an appropria… Show more

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Cited by 123 publications
(75 citation statements)
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“…1 from which it is clear that the NiFe film consists of a polycrystalline granular (10-30 nm) ferromagnetic (FM) phase with an average film composition of 45%Ni-55%Fe, along with a thin (1 to 2 nm) secondary Fe deficient phase at the grain boundaries [blue boundary region in Fig. 1(d 3 Fe nanograins is in the range of ∼20−80 Oe (previously reported) higher than the coercivity (measured H C = 0.5Oe) of the bulk Ni 45 Fe 55 alloy film [22][23][24][25]. Detailed magnetic measurements have been carried out in a superconducting quantum interference device (SQUID) magnetometer (MPMS XL5, Quantum Design) across a wide temperature range of 5-300 K under a maximum field H max of ±50 kOe .…”
mentioning
confidence: 94%
“…1 from which it is clear that the NiFe film consists of a polycrystalline granular (10-30 nm) ferromagnetic (FM) phase with an average film composition of 45%Ni-55%Fe, along with a thin (1 to 2 nm) secondary Fe deficient phase at the grain boundaries [blue boundary region in Fig. 1(d 3 Fe nanograins is in the range of ∼20−80 Oe (previously reported) higher than the coercivity (measured H C = 0.5Oe) of the bulk Ni 45 Fe 55 alloy film [22][23][24][25]. Detailed magnetic measurements have been carried out in a superconducting quantum interference device (SQUID) magnetometer (MPMS XL5, Quantum Design) across a wide temperature range of 5-300 K under a maximum field H max of ±50 kOe .…”
mentioning
confidence: 94%
“…For example, CoFe alloy nanoparticles were reported to have the ε values around 6.5 in the frequency range of 2-14 GHz [24]. The permittivity of FeNi 3 alloy particles is almost constant of 5.9 in the 2-10 GHz range [25] that is nearly half lower than that of Fe and Ni nanoparticles. It is speculated that the lower ε values of these alloys result from the increasing resistivity, because metal alloys normally have greater resistivity than pure metals.…”
Section: Resultsmentioning
confidence: 99%
“…Among various potential candidates for EM wave absorbers, the one in the form of magnetic nanoparticles core/ dielectric shell-structured nanocapsules, such as Ni/ZnO, FeNi 3 /SiO 2 , Ni/PANI, Ni/C, and Ni/Ni 2 O 3 nanocapsules, has been of particular interest in recent years owing to its tailorable properties in conjunction with smaller sizes and weights [6][7][8][9][10] . An essence of determining the EM wave absorbing properties of the nanocapsules is to obtain a balance between the permeability of the magnetic nanoparticle cores with the permittivity of the dielectric shells 11 .…”
Section: Introductionmentioning
confidence: 99%