Microtubular Fe/Mn-promoted CaO-Ca12Al14O33 bi-functional material for H2 production from sorption enhanced water gas shift

The Effect of Mn, Al Doping on the CO2 Hydrogenation Performance of CaCO3‐Supported Fe‐Based Catalysts

“…The catalyst was synthesized according to the Ref. [34], and the procedure is described below. First, 5 g of Ca(C 2 H 3 O 2 ) 2 • H 2 O and a certain amount of Al(NO 3 ) 3 •9 H 2 O, Fe(NO 3 ) 3 •9H 2 O and M(C 2 H 3 O 2 ) 2 •nH 2 O (M=Mn, Co, Cu, and Zn) were dissolved in 50 mL of deionized water to form a homogeneous solution.…”

“…And the application of Ca as a carrier in the water gas reaction was found by searching the literature. [34] And the water gas reaction and the reversed water gas reaction are a pair of reversible reactions. The first reaction step of the CCH route for CO 2 hydrogenation is the reverse water gas reaction, which indicates that Ca is possible as a carrier for catalytic CO 2 conversion.…”

Catalytic Synthesis of CO by Combining CO2 Capture and Hydrogenation over Three-Dimensional Ni/CaO Networks

“…The major limitation for industrial applications of CaO-based sorbents at high temperatures is the fast decrease of the CO 2 capture capacity after only a few carbonation and decarbonation cycles, even decreasing to 10% of their initial value, , mainly due to the sintering of the CaO-based sorbents. The incorporation of CaO into inert support particles is one of the strategic approaches − to overcome this limitation by mitigating the sintering of the CaO-based sorbents. In addition, several systems using CaO adsorbents with Ni catalysts have been reported; however, such systems suffered from considerable decreases in CO 2 capture capacity and CO productivity after several cycles .…”

Effects of Cu ratios on the C1–C6 growth mechanism on copper–nickel bimetallic surfaces

“…The conversion of CH 4 to syngas (H 2 and CO) by reforming is most favored as CO and H 2 are essential industrial feedstock gases. 12 Syngas can be used to produce high economic value organics by Fischer-Tropsch synthesis. [13][14][15][16][17] CH 4 is mainly reformed by (a) partial oxidation reforming (eqn (1)), (b) steam reforming (eqn (2)), and (c) dry reforming (eqn (3)).…”