Al-Si alloys have a wide range of applications in automotive and aerospace components due to their favorable properties such as low density, high specific stiffness, resistance to high temperatures and abrasion, and low thermal expansion coefficient. [1] Alloying elements have been strategically included into the composition of Al-Si-based alloys in order to improve specific properties of interest. [2][3][4][5] For tribological applications, elements with solid lubricant ability, such as bismuth and tin are of interest to Al-Si alloys for improved bearing performance. This performance depends strongly on the alloy's microstructural features, such as the secondary dendrite arm spacing, the eutectic lamellar spacing, or the spacing between the soft and immiscible Bi particles in the aluminum matrix. [6] Efforts have been put by Costa et al. [5] and Dias et al. [7] into studies of microstructural arrangements of such alloys, particularly Al-Si-Bi, correlated with a range of solidification thermal parameters provided by a water-cooled mold. However, this range is limited to cooling rates provided by the water-cooled mold. Higher values may be reached by processes involving rapid solidification.Hearn et al. [8] reported typical hypoeutectic microstructures characterized by proeutectic α-Al dendrites surrounded by α-Al þ Si eutectic. The Al-10 wt%Si alloy was solidified by differential scanning calorimetry (DSC) with cooling rates of 0.01, 0.02, 0.08, 0.2, 0.3, and 0.8 K s À1 . The eutectic microstructure was reported to have a flaky morphology for all the conditions examined. Costa et al. [5] examined the effect of adding 1 wt%Bi to an Al-9 wt%Si alloy. They reported that the secondary and tertiary dendrite arm spacings are not affected. However, a coarsening effect on the primary arm spacing is shown to occur for the ternary alloy when compared to the binary alloy for similar cooling rates. The addition of Bi was shown not to affect the ultimate tensile strength. However, the elongation to fracture is improved. Furthermore, a higher machinability is achieved,