a b s t r a c tThe phase equilibria of the Zr-Ti-Si ternary system at 773 K have been investigated mainly by powder X-ray diffraction (XRD), scanning electron microscope (SEM) and energy dispersive analysis (EDX). The isothermal section consists of 14 single-phase regions, 23 binary-phase regions and 13 ternary-phase regions. The binary compounds Zr 3 Si and Zr 5 Si 3 are not observed at 773 K. Therefore, there are 10 binary compounds, i.e. in the Zr-Ti-Si system at 773 K. Ternary compound Si 3 Ti 2 Zr 3 is found at this isothermal section. The solubilities of Zr in TiSi 2 , TiSi, Ti 5 Si 4 , Ti 5 Si 3 and Ti 3 Si were determined to be up to 10, 11, 12, 13 and 7 at.% Zr, respectively; the solubilities of Ti in Zr 3 Si 2 , Zr 5 Si 4 , ZrSi and ZrSi 2 were about 5.4, 14, 7 and 14 at.% Ti.