2013
DOI: 10.4236/epe.2013.52a003
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Microstructure Analysis and Properties of Anti-Reflection Thin Films for Spherical Silicon Solar Cells

Abstract:

Structure and properties of anti-reflection thin films of spherical silicon solar cells were investigated and discussed. Conversion efficiencies of spherical Si solar cells coated with F-doped SnO2 anti-reflection films were improved by annealing. Optical absorption and fluorescence of the solar cells increased after annealing. Lattice constants of F-doped SnO2 anti-reflection layers, which were investigated by X-ray dif… Show more

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Cited by 9 publications
(5 citation statements)
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References 30 publications
(29 reference statements)
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“…30,31 The area of the Sn 4+ spectra was larger than that of the Sn 2+ spectra, indicating that the formation of SnO 2 was preferred to SnO due to the lower Gibbs free energy of formation of SnO 2 compared to that of SnO. 32 As the Sn concentration increased further, the Sn 2+ /Sn 4+ area ratio continued to increase, indicating that the formation of SnO was also favorable at the higher Sn concentration, as shown in Fig. 4b.…”
Section: Resultsmentioning
confidence: 92%
“…30,31 The area of the Sn 4+ spectra was larger than that of the Sn 2+ spectra, indicating that the formation of SnO 2 was preferred to SnO due to the lower Gibbs free energy of formation of SnO 2 compared to that of SnO. 32 As the Sn concentration increased further, the Sn 2+ /Sn 4+ area ratio continued to increase, indicating that the formation of SnO was also favorable at the higher Sn concentration, as shown in Fig. 4b.…”
Section: Resultsmentioning
confidence: 92%
“…First publications in the field of a microcell approach base on light absorbing materials like silicon or gallium‐arsenide that have been investigated by J.A. Rogers and M. Kanayama et al . For Cu(In,Ga)Se 2 ‐based absorber material M. Paire and D. Lincot et al investigated and published an enhancement in conversion efficiency by 4% absolute at 120× light concentration, which was recently further improved to plus 5% absolute at 475× concentration showing a final conversion efficiency of 21.3% .…”
Section: Introductionmentioning
confidence: 99%
“…7) To improve the conversion efficiencies of the spherical Si solar cells, 8) high quality silicon balls, optical confinement structures, inactivation of defects by passivation, formation of a texture structure on Si surface, [9][10][11] optimization of structures of reflectors, 12,13) reduction in resistance, and high transmission of anti-reflection films are mandatory. [14][15][16][17] The purpose of the present work is to investigate the microstructures and optical and photoelectric conversion properties of spherical Si solar cells with anti-reflection (AR) F-doped tin oxide (SnO x :F, FTO) thin films. The annealing effects on conversion efficiencies were investigated, and the optical properties were investigated by optical absorption and fluorescence spectroscopy.…”
Section: Introductionmentioning
confidence: 99%