Transferring traditional plasmonic noble metal nanomaterials
from
the laboratory to industrial production has remained challenging due
to the high price of noble metals. The development of cost-effective
non-noble-metal alternatives with outstanding plasmonic properties
has therefore become essential. Herein, we report on the gram-scale
production of differently shaped TiN nanoparticles with strong plasmon-enabled
broadband light absorption, including differently sized TiN nanospheres,
nanobipyramids, and nanorod arrays. The TiN nanospheres and nanobipyramids
are further coembedded in highly porous poly(vinyl alcohol) films
to function as a photothermal material for solar seawater desalination.
A seawater evaporation rate of 3.8 kg m
–2
h
–1
is achieved, which marks the record performance among
all plasmonic solar seawater desalination systems reported so far.
The removal percentage of phenol reaches 98.3%, which is attributed
to the joint action of the excellent photocatalytic ability and the
superhydrophilicity of the porous TiN-based composite film.