Microflow reactor synthesis of palladium nanoparticles stabilized with poly(benzyl ether) dendron ligands

Torigoe, Kanjiro; Watanabe, Yohsuke; Endo, Takeshi; Sakai, Kenichi; Sakai, Hideki; Abe, Masahiko

doi:10.1007/s11051-009-9645-7

Cited by 28 publications

(9 citation statements)

References 24 publications

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“…Their synthesis in flow conditions can be especially simple and efficient. In the system consisting of a syringe pump and a long straight glass capillary, the palladium nanoparticles were obtained by thermal decomposition of palladium actetate in the presence of dendron ligands, used as stabilizers [99]. Under optimized conditions, NPs of sizes 3.1 ± 0.2 nm were produced.…”

Section: Synthesis Of Nanoparticles In Continuous Flow Systemsmentioning

confidence: 99%

Flow chemistry vs. flow analysis

Trojanowicz

2016

Talanta

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Section: Synthesis Of Nanoparticles In Continuous Flow Systemsmentioning

confidence: 99%

Flow chemistry vs. flow analysis

Trojanowicz

2016

Talanta

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“…The throughput can be up to 9 L/min, and the production capacity was greatly increased compared to typical microreactors operating at 4-100 mL/min. Palladium nanoparticles have been prepared using a glass capillary microfluidic reactor system (Torigoe et al, 2010).…”

Section: Othersmentioning

confidence: 99%

Nanoparticle synthesis in microreactors

Zhao

Qiao

et al. 2011

Chemical Engineering Science

382

213

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“…A glass capillary microflow reactor system has been used to synthesize palladium nanoparticles by thermal decomposition of palladium acetate (Pd(OAc) 2 ) in diphe nyl ether in the presence of poly(benzyl ether) dendron ligands (PBED GnNH 2 , n = 1-3) as a stabilizer [52]. The effects of the hydrodynamic parameter (capillary diam eter, velocity, volume flow rate, and reaction temperature) and concentration (precursor and stabilizer) on the par ticle size were investigated.…”

Section: Synthesismentioning

confidence: 99%

Metallic nanoparticles made in flow and their catalytic applications in organic synthesis

Shahbazali

Hessel

Noël

et al. 2014

Nanotechnology Reviews

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This paper reviews recent developments on the synthesis of noble metal nanoparticles in micro and milli fluidic devices and their catalytic application in organic flow synthesis. A variety of synthesis methods using microfluidics is presented for gold, silver, palladium, platinum, and copper nanoparticles, including the for mation in singlephase flows and multiphase flows. In the field of organic chemistry, metal nanoparticles can be used as catalysts. This can lead to remarkably improved reaction performance in terms of minimizing the reaction time and higher yields. In this context, various applica tions of those metal nanoparticles as catalysts in micro fluidic devices are highlighted at selected examples. As a new direction and operational window, nanocatalysts may be synthesized in situ in flow and directly utilized in an organic synthesis. This allows making use of highly active, yet instable catalyst species, which may only have a very short life of a few seconds -a type of flashed nano catalyst organic synthesis.

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Microflow reactor synthesis of palladium nanoparticles stabilized with poly(benzyl ether) dendron ligands

Cited by 28 publications

References 24 publications

Flow chemistry vs. flow analysis

Flow chemistry vs. flow analysis

Nanoparticle synthesis in microreactors

Metallic nanoparticles made in flow and their catalytic applications in organic synthesis

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