Mg(BF4)2 doped in [BMIm][BF4]: A homogeneous ionic liquid-catalyst for efficient synthesis of 1,8-dioxo-octahydroxanthenes, decahydroacridines and 14-aryl-14H-dibenzo[a,j]xanthenes

Acridine‐1,8‐diones: Synthesis and Biological Applications

“…Recently, various researchers worked on the synthesis of magnesium based catalyst, fascinating its bio-friendly behavior in living organisms at normal oxidation state. From this inspiration, Rad-Moghadam and group [128] [129] devised ultrasound assisted methyltrioctylammonium chloride catalyzed synthesis of 1,8-dioxo-decahydroacridines under ambient and eco-friendly conditions with excellent yields [Scheme 17, Method 5]. Alinezhad et al [130] demonstrated an eco-benign aqueous mediated In 2015, a simple, concise and dexterous transformation using easily available aldehydes, hydrazine hydrate, 1,8-naphthanoic anhydride and dimedone with [bmim]HSO 4 to prepare naphthalimide attached acridine-1,8-dione in moderate to high yields was reported by Chandramouli et al [132] [ Scheme 18].…”

“…Recently, various researchers worked on the synthesis of magnesium based catalyst, fascinating its bio‐friendly behavior in living organisms at normal oxidation state. From this inspiration, Rad‐ Moghadam and group [128] implemented Mg(BF 4 ) 2 fabricated ionic‐liquid [BMIm][BF 4 ] for the convenient and facile synthesis of acridinediones using aldehydes, dimedone and NH 4 OAc at 80 °C. This moderated catalyst is stable in air and moisture and recyclable upto four times [Scheme 17, Method 4].…”

[Bmim]BF4: A Versatile Ionic Liquid for the Synthesis of Diverse Bioactive Heterocycles

“…Rad‐Moghadam et al . (Table ) successfully doped catalytic amount of Mg(BF 4 ) 2 in ionic liquid [bmim]BF 4 . They employed this new homogeneous reusable catalytic system for the efficient synthesis of 1,8‐dioxo‐octahydroxanthenes ( 58 ) via the pseudo three‐component reaction between dimedone ( 51 ) and various aldehydes ( 19 ) at 80 °C.…”

Sulfanilamide and silver nanoparticles-loaded polyvinyl alcohol-chitosan composite electrospun nanofibers: Synthesis and evaluation on synergism in wound healing

“…Most importantly, mesoporous nanoparticles including those made from silica and hydroxyapatite, and microporous nanostructures such as bio-MOF have found applications in medical imaging, drug delivery, and bone and organ replacements [1][2][3][4][5][6][7][8]. Over the last two decades, their tunable high surface area, surface to volume ratio, softness, surface coverage, high porosity, and high drug loading and delivery capacity to their target tissues, has made them attractive in drug delivery research.…”