“…Since the Au thin film is sacrificed for the fabrication of the NIL molds, the LER is improved substantially due to the smaller grain size of the Cr thin film and ameliorated further during RIE of the quartz. This improvement in LER is commonly observed when using hard masks and photoresists to etch features 25 and is attributed to higher RIE rates at higher surface energy locations, such as areas with sharp edges. The grain size of Au, which is the primarily limiting factor for obtaining better LER, is much smaller on quartz than on SiO 2 / Si ͑data not shown͒, presumably due to the differences in surface free energies between quartz and SiO 2 / Si.…”