Metathesis of Silicon‐Containing Olefins

Flame Resistant Silicone-Containing Coating Materials

“…It can be concluded that PDMS can be a good base to explore structures with clearly better thermal stability. The rich chemistry of silicon compounds enables the use of various catalytic processes, such as metathesis, silylative coupling, and others [75,76], including frequently used hydrosilylation [77]. Polydimethylsiloxanes functionalized with biphenyl phosphates were synthesized using 1,1,3,3-tetramethyldivinyldisiloxane in the hydrosilylation process with further crosslinking in the presence of platinum Kartsedt's catalyst [72].…”

Editorial of Special Issue Ruthenium Complex: The Expanding Chemistry of the Ruthenium Complexes

“…With introduction of the new generations of highly active and chemoselective Ru metathesis catalysts endowed with high tolerance towards many functionalities and good stability in the presence of air, moisture and various solvents, including water-containing systems [231,232,233,234,235,236,237,238,239], the diversification of metathesis reactions experienced a strong impetus [240,241,242,243,244,245]. Among metathesis reactions, cross-metathesis (CM) [246,247,248,249] and ring-closing metathesis (RCM) [250,251,252,253,254] have become the most encountered strategies for the synthesis of linear and branched, or carbocyclic and heterocyclic compounds. Ru-catalyzed enyne metathesis (EYRCM) provided an elegant and productive way to obtain small, medium and large cyclic molecules [255].…”

“…Synthesis, involving enyne metathesis, of biologically and medicinally significant molecules like (+)-anatoxin-A, (+)-anthramycin, artemisinin, transtaganolide D, allo-colchicine, (−)-galanthamine, (−)-longithorone A, (+)-ochromycinone, (+)-rubiginone B2, and (−)-stemoamide have become attractive when starting from adequate substrates [274]. It should be emphasized that cross-metathesis allowed diversification of synthetic strategies by employing substrates that are tolerated by the new generations of Ru complexes [231,236,237,238,239,243,244,246,247,248,249]. A remarkably creative work encompasses the total synthesis of (−)-amphidinolide K and V applying an ingenious combination of Mo with Ru metathesis catalytic systems [275].…”