Metal–organic framework-derived porous Mn1.8Fe1.2O4nanocubes with an interconnected channel structure as high-performance anodes for lithium ion batteries

Zheng, Fangcai; Zhu, Ding; Shi, Xiaohui; Chen, Qianwang

doi:10.1039/c4ta06150k

Cited by 158 publications

(90 citation statements)

References 52 publications

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“…[57] According to previous reports, MTMOs demonstrate significantly enhanced lithiums torage properties compared with those of single metal oxide materials. Similarly,v ariousm ixed-metal oxides with poroush ollow structures, such as NiFe 2 O 4 /Fe 2 O 3 nanotubes, [59] CoFe 2 O 4 nanocubes, [60] andM n 1.8 Fe 1.2 O 4 nanocubes, [61] have been constructed by rationally designing heterometallic MOFs as the templates. [58] Specifically,P russian blue analogue Ni 3 [Co(CN) 6 ] 2 nanocubes were first prepared by ac oprecipitation reaction with NiCl 2 ,K 3 [Co(CN) 6 ], and sodium citrate in distilled water at room temperature.…”

Section: Mof-derived Tmos For Libsmentioning

confidence: 99%

Recent Progress in Metal–Organic Frameworks and Their Derived Nanostructures for Energy and Environmental Applications

et al. 2017

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Metal-organic frameworks (MOFs), as a very promising category of porous materials, have attracted increasing interest from research communities due to their extremely high surface areas, diverse nanostructures, and unique properties. In recent years, there is a growing body of evidence to indicate that MOFs can function as ideal templates to prepare various nanostructured materials for energy and environmental cleaning applications. Recent progress in the design and synthesis of MOFs and MOF-derived nanomaterials for particular applications in lithium-ion batteries, sodium-ion batteries, supercapacitors, dye-sensitized solar cells, and heavy-metal-ion detection and removal is reviewed herein. In addition, the remaining major challenges in the above fields are discussed and some perspectives for future research efforts in the development of MOFs are also provided.

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Section: Mof-derived Tmos For Libsmentioning

confidence: 99%

Recent Progress in Metal–Organic Frameworks and Their Derived Nanostructures for Energy and Environmental Applications

et al. 2017

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“…The voltammogram for the first cycle is substantially different from those of the subsequent ones, especially for the discharge branch. In the first cycle, the intense cathodic peak located at around 0.35 V, which can be attributed to the initial reduction of Ni-O to Ni and the formation of amorphous Li 2 O and solid electrolyte interface (SEI) film [22,24,25]. Additionally, the broad anodic peak at about 2.2 V can be assigned to the oxidation of the metallic nickel to Ni-O and the decomposition of Li 2 O.…”

Section: Resultsmentioning

confidence: 95%

“…It was reported that the mesopore in the electrode materials facilitate to transfer of lithium ions and electrons during the charge/discharge processes [22,23]. Therefore, the hierarchical NiO microspheres assembled from 2D porous nanosheets may be beneficial for the electrolyte to penetrate completely into the pores and diffuse efficiently to active sites with less resistance, and also can buffers huge volume expansion during the charge/discharge processes.…”

Section: Resultsmentioning

confidence: 99%

Facile fabrication of hierarchically porous NiO microspheres as anode materials for lithium ion batteries

Zheng

Zhang

2016

J Mater Sci: Mater Electron

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In this work, we report a novel and facile route for the large-scale fabrication of hierarchically porous NiO microspheres, which involves the thermal decomposition of b-Ni(OH) 2 precursor at 450°C in air for 2 h. The superstructures exhibit high specific surface area, large porous volume, and broad pore size distribution. The electrochemical properties of the hierarchically porous NiO microspheres were examined by cyclic voltammetry and galvanostatic charge/discharge studies. The results demonstrate that the hierarchically porous NiO microspheres are promising anode materials with enhanced lithium storage capacity and excellent cycling stability. The hierarchically porous NiO microspheres can retain a reversible capacity of 612 mA h g -1 after 50 cycles at a current density of 100 mA g -1 . The improved electrochemical performance is attributed to their hierarchical structure and large amounts of mesopores within the nanosheets, which can effectively improve structural stability, reduce the diffusion length for lithium ions and electrons, and buffer volume expansion during the charge/ discharge processes.

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“…Moreover, inspired by their high surface areas, porosity, and abundant carboncontaining linkers, MOFs have been demonstrated as promising templates or precursors to fabricate nanostructured materials via thermolysis [49][50][51][52][53][54][55][56][57][58][59][60]. ZIF-8 (Zn(MeIM) 2 ; MeIM = 2-methylimidazole) is a chemically and thermally robust highly porous zeolite-type MOF.…”

Section: Introductionmentioning

confidence: 99%

MOFs as reactant: In situ synthesis of Li2ZnTi3O8@C–N nanocomposites as high performance anodes for lithium-ion batteries

Wang

Chen

et al. 2016

Journal of Electroanalytical Chemistry

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Metal–organic framework-derived porous Mn_1.8Fe_1.2O₄nanocubes with an interconnected channel structure as high-performance anodes for lithium ion batteries

Cited by 158 publications

References 52 publications

Recent Progress in Metal–Organic Frameworks and Their Derived Nanostructures for Energy and Environmental Applications

Recent Progress in Metal–Organic Frameworks and Their Derived Nanostructures for Energy and Environmental Applications

Facile fabrication of hierarchically porous NiO microspheres as anode materials for lithium ion batteries

MOFs as reactant: In situ synthesis of Li2ZnTi3O8@C–N nanocomposites as high performance anodes for lithium-ion batteries

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