Messung der Adsorption potentialbestimmender Ionen an Elektroden nach der Methode der nichtstationären Konzentrationspolarisation

Lorenz, W.J.; Mühlberg, Heinz

doi:10.1002/bbpc.19550590725

Zeitschrift für Elektrochemie, Berichte der Bunsengesellschaft

1955

DOI: 10.1002/bbpc.19550590725

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Messung der Adsorption potentialbestimmender Ionen an Elektroden nach der Methode der nichtstationären Konzentrationspolarisation

W.J. Lorenz

Heinz Mühlberg

Abstract: Das in der vorangehenden Mitteilung2) entwickelte Meßverfahren wird an platinierten Platinelektroden in Jod‐Jodid‐Lösung experimentell verifiziert. Die Adsorption von √3 wird bei verschiedenen Konzentrationen bestimmt. Unter Heranziehung von Doppelschichtkapazitätsmessungen wird die adsorbierte Menge je wahre Elektrodenoberfläche näherungsweise ermittelt. — Weiterhin wird die Adsorption von Fe2+, Fe3+ an platiniertem Platin und von Ag+ an blanken Silberelektroden untersucht; in diesen Fällen läßt sich ein ober… Show more

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1962

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The Application of Lagrange's Theorem in Electrochemical Kinetics II. Single and Cyclic Current Step Polarization

Cellings¹

1962

Zeitschrift für Elektrochemie, Berichte der Bunsengesellschaft

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The inversion of the basic equation of electrochemical kinetics by means of Lagrange's theorem is applied to two galvanostatic experimental methods. The first is the single current step method (galvanostatischer Einschaltvorgang) which has often been used in the study of electrode kinetics. The second is the more recent technique of the cyclic current step method.It is shown to be possible to extend the field of application of these techniques. Another advantage gained by the use of Lagrange's theorem is that if approximations are used it is possible to define exactly the range of validity of these approximations and to estimate the errors involved.

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The Application of Lagrange's Theorem in Electrochemical Kinetics II. Single and Cyclic Current Step Polarization

Cellings¹

1962

Zeitschrift für Elektrochemie, Berichte der Bunsengesellschaft

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Messung der Adsorption potentialbestimmender Ionen an Elektroden nach der Methode der nichtstationären Konzentrationspolarisation

Cited by 1 publication

References 9 publications

The Application of Lagrange's Theorem in Electrochemical Kinetics II. Single and Cyclic Current Step Polarization

The Application of Lagrange's Theorem in Electrochemical Kinetics II. Single and Cyclic Current Step Polarization

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