Mesoporous epoxidized soybean oil-supported copper-based magnetic nanocatalyst and amberlite-supported azide as a green and efficient catalytic system for 1,2,3-triazole synthesis

Dehkordi, S. Saeid Saei; Jafari, Abbas Ali; Albadi, Jalal; Samimi, Heshmat Allah

doi:10.1007/s11030-022-10408-6

Cited by 6 publications

(4 citation statements)

References 46 publications

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“…Dehkordi et al synthesised nano-magnetic catalysts through the immobilisation of copper on Fe 3 O 4 @SiO 2 loaded epoxidised soybean oil. 125 The formed catalytic system was utilised to synthesise 1,2,3-triazoles (55/232) using amberlite-supported azide under aqueous conditions at room temperature in 25-60 min (Scheme 72). These MNPs were reused in up to five cycles for the synthesis of the final products.…”

Section: Account Synlettmentioning

confidence: 99%

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Synthesis of Nitrogen- and Oxygen-Containing Heterocycles Catalysed by Metal Nanoparticles Reported in 2022

Dhameliya,

Shah,

Shah

et al. 2024

Synlett

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The versatility of aza- and oxa-heterocyclic compounds has garnered significant attention in recent times. A large number of currently approved pharmaceutical products include nitrogen- and oxygen-containing heterocycles. Recent nanotechnological developments have propelled an upsurge in the applications of nanocatalysis for heterocyclic synthesis. Metal nanoparticles (MNPs) have emerged as promising catalysts for the synthesis of aza- and oxa-heterocycles owing to their unique physicochemical properties. Various MNPs including gold, silver, nickel and palladium have been evaluated for their catalytic activities in different reaction types, including cyclisation, coupling, hydrogenation and oxidative transformations. The MNPs have exhibited remarkable catalytic efficiency when utilised under optimal conditions. These catalysts have showcased high reusability and recyclability, yielding satisfactory amounts of the desired heterocyclic compound. The present work provides a detailed overview of recent advances in the area of MNP-assisted synthetic construction of aza- and oxa-heterocycles, published during the previous calendar year, 2022. The review serves as a valuable resource and also paves the way for future investigations in the development of novel catalytic strategies for heterocycle synthesis.1 Introduction2 Nanocatalysis3 Aza- and Oxa-Heterocycle Synthesis Catalysed by MNPs3.1 AuNPs3.2 CuNPs3.3 CoNPs3.4 FeNPs3.5 NiNPs3.6 PdNPs3.7 PtNPs3.8 SiNPs3.9 ZnNPs3.10 Bimetallic NPs3.11 Other MNPs4 Summary and Outlook

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Section: Account Synlettmentioning

confidence: 99%

“…Scheme 35 (SiO 2 -SO 3 )-(morpholine-H) + catalysed synthesis of polyhydroquinoline derivatives(125) …”

mentioning

confidence: 99%

Synthesis of Nitrogen- and Oxygen-Containing Heterocycles Catalysed by Metal Nanoparticles Reported in 2022

Dhameliya,

Shah,

Shah

et al. 2024

Synlett

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“…Dehkordi and colleagues reported a new eco‐friendly mesoporous magnetic heterogeneous catalyst. The catalyst was developed by immobilizing copper onto magnetic epoxidized soybean oil Fe 3 O 4 @SiO 2 ‐ESBO/CuO serving as a nano bio‐support [85] . It was employed in the synthesis of 1,4‐substituted‐1,2,3‐triazole derivatives in the presence of amberlite‐supported azide.…”

Section: Copper Based Heterogeneous Catalyst For Azide‐alkyne Cycload...mentioning

confidence: 99%

“…The catalyst was developed by immobilizing copper onto magnetic epoxidized soybean oil Fe 3 O 4 @SiO 2 -ESBO/CuO serving as a nano biosupport. [85] It was employed in the synthesis of 1,4-substituted-1,2,3-triazole derivatives in the presence of amberlite-supported azide. The nanocatalyst was prepared by using a co-precipitation method.…”

Section: Nanosized Magnetic Supportmentioning

confidence: 99%

A New Insight Into The Huisgen Reaction: Heterogeneous Copper Catalyzed Azide‐Alkyne Cycloaddition for the Synthesis of 1,4‐Disubstituted Triazole (From 2018–2023)

Kasana,

Nigam,

Singh

et al. 2024

Chemistry & Biodiversity

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The Huisgen cycloaddition, often referred to as 1,3‐Dipolar cycloaddition, is a well‐established method for synthesizing 1,4‐disubstituted triazoles. Originally conducted under thermal conditions [3+2] cycloaddition reactions were limited by temperature, prolonged reaction time, and regioselectivity. The copper catalyzed azide‐alkyne cycloaddition (CuAAC) has emerged as a prominent method for producing 1,2,3‐triazole with excellent yields and exceptional regioselectivity. Copper catalysts conventionally facilitate azide‐alkyne cycloadditions, but challenges include instability and recycling issues. In recent years, there has been a growing demand for heterogeneous catalysts in various chemical reactions. The present review covers recent advancements from year 2018 to 2023 in the field of click reactions for obtaining 1,2,3‐triazoles through Cu catalyzed 1,3‐dipolar azide‐alkyne cycloaddition and the properties of the catalyst, reaction conditions such as solvent, temperature, reaction time, and the impact of different heterogeneous copper catalysts on product yield.

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Efficient Suzuki coupling over novel magnetic nanoparticle: Fe3O4/L-(+)-tartaric acid/Pd(0)

2022

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Mesoporous epoxidized soybean oil-supported copper-based magnetic nanocatalyst and amberlite-supported azide as a green and efficient catalytic system for 1,2,3-triazole synthesis

Cited by 6 publications

References 46 publications

Synthesis of Nitrogen- and Oxygen-Containing Heterocycles Catalysed by Metal Nanoparticles Reported in 2022

Synthesis of Nitrogen- and Oxygen-Containing Heterocycles Catalysed by Metal Nanoparticles Reported in 2022

A New Insight Into The Huisgen Reaction: Heterogeneous Copper Catalyzed Azide‐Alkyne Cycloaddition for the Synthesis of 1,4‐Disubstituted Triazole (From 2018–2023)

Efficient Suzuki coupling over novel magnetic nanoparticle: Fe3O4/L-(+)-tartaric acid/Pd(0)

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