1996
DOI: 10.1177/073490419601400602
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Mechanisms for Flame Retardancy and Smoke suppression -A Review

Abstract: The prevailing mechanisms for halogen and phosphorus flame retardancy are reviewed. Halogens act in the vapor phase and phosphorus can act in either the vapor or condensed phase depending on the specific phos phorus compound and the chemical composition of the polymer. Halogen- antimony synergy is discussed. Convincing evidence is presented for bromine- phosphorus synergy in specific polymers. The mode of decomposition of polycarbonate is shown and the effect of salts of organic acids in changing the mode of d… Show more

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Cited by 207 publications
(114 citation statements)
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“…Fire retardants containing such heteroelements or other inhibitors can increase the yield of smoke and its toxic components, but by slowing the rate of burning can also cause a reduction in smoke and toxic gas production rates. Commercial smoke suppressants can be added to fire retardants to reduce the quantity of smoke produced, examples include zinc borate, and molybdenum and tin compounds (Green 1996).…”
Section: Smoke Production and Toxicitymentioning
confidence: 99%
“…Fire retardants containing such heteroelements or other inhibitors can increase the yield of smoke and its toxic components, but by slowing the rate of burning can also cause a reduction in smoke and toxic gas production rates. Commercial smoke suppressants can be added to fire retardants to reduce the quantity of smoke produced, examples include zinc borate, and molybdenum and tin compounds (Green 1996).…”
Section: Smoke Production and Toxicitymentioning
confidence: 99%
“…32 For example, metal cations from color pigments or an inert filler such as calcium carbonate or talc may lead to the formation of stable metal halides, rendering the halogen unavailable for reaction with antimony oxide. The result is that neither the halogen nor the antimony is transported into the vapor zone.…”
Section: Halogen-containing Flame Retardantsmentioning
confidence: 99%
“…Polymer combustion is a complex process involving a multitude of steps and is best described in qualitative terms. In general, four major steps comprise polymer combustion: ignition, pyrolysis, combustion and feedback [35]. Depending on the flammability limit of the material, ignition is normally caused by the presence of an external heat source such as a flame or a spark or, if the temperature is high enough, occurs spontaneously.…”
Section: Recent Developments In Different Techniquesmentioning
confidence: 99%