Mechanism on redistribution synthesis of dichlorodimethylsilane by AlCl3/ZSM–5(3T)@γ–Al2O3 core-shell catalyst

Preparation and redistribution mechanism of dimethyldichlorosilane catalyzed by the AlCl3/ZSM-5(5T)@MIL-53(Al) core–shell catalyst

“…During the early stage of the research, 7,8 our team found that a variety of ZSM-5 cluster models showed catalytic disproportionation activity, especially when modified by AlCl 3 . Representative micropore clusters such as 4T and 5T (T represents a general tetrahedral unit) 9 possessed commendable catalytic activity.…”