The graphene oxide (GO) sheets with different size distributions were effectively separated by a centrifugation method. The exfoliated single-layer structure and the size of GO sheets were verified by scanning electron microscopy (SEM), atomic force microscope (AFM), and metallurgical microscope, respectively. Two different-sized GO sheets water suspensions were obtained, which were then directly dispersed in carbon fiber (CF) sizing agent, respectively. The influences of the different-sized GO sheets on CF and CF composites were explored. The workability in later process of CF and CF surface morphology were characterized by abrasion resistance, fluffs and breakage, stiffness, and SEM. SEM micrographs demonstrated that a nonuniform distribution of the large-sized GO was lapped on CF whereas the small-sized GO was uniformly leaned on CF. The interlaminar shear strength of the smallsized GO/CF reinforced composite could reaches the maximum value. It indicated that the interfacial region between CF and polymer matrix could be enhanced by adjusting the size of GO sheets. POLYM. COMPOS., 00:000-000, 2015. V C 2015 Society of Plastics Engineers
INTRODUCTIONCarbon fiber (CF) composites have been used as structural materials and applied to replace many metals in various applications, such as the aircraft, rocket, sport, military industries, and other transport vehicles, because of their excellent mechanical and thermal stability, higher strengthto-weight ratio property [1][2][3][4][5]. It is well-known that the property of CF composites is, to a large extent, dependent on the bonding situation of fiber-matrix interface. Good interfacial property is necessary to guarantee efficient load transfer from matrix to fillers, which helps to improve mechanical properties. The problem of CF composites, however, is that it shows poor interfacial property between CF and polymer matrix [6]. Therefore, nowadays many professionals carry out extensive researches on improving the interfacial property of CF composites [7][8][9][10].Graphene, a single-atom-thick sheet of hexagonally arrayed sp 2 -bonded carbon atoms, exhibits numerous unique properties [11]. In recent years, graphene and graphenebased materials have attracted tremendous attention because of their exceptional chemical, optical, electronic, and mechanical properties, which demonstrate a huge potential for various applications, such as transparent electrodes, super capacitors, and composites [12][13][14]. Graphene oxide (GO) sheets, an oxidized shape and intermediate in synthesis of graphene, have good handling characteristics and chemical reactivity in solution due to the intrinsic functional groups [15][16][17]. GO sheets were synthesized by a modified Hummers method normally [18,19].Zhang et al. [20] have prepared a stable GO-modified CF sizing agent by directly dispersing GO sheets in CF sizing agent. It had demonstrated that the addition of GO in the sizing agent could improve the interfacial properties of composites and it was more effective than the method of dispersin...