A K x-ray-L x-ray coincidence technique previously used to measure the Coster-Kronig probability fi3 has been extended to include determination of the fluorescence yields w2 and w 3 . Removal of experimental errors believed to have generated the scatter in literature data was of particular concern. Measurements were performed for elements with Z = 78, 80, 81, 82, 92 and 96. For Z in the region of 80, excellent agreement with Dirac-Hartree-Slater theory is evident for w 2 and w,; however, f 2 3 is systematically lower than predicted. In contrast, for 2 2 92, the theoretical and experimental values for f23 were in quite good agreement while discrepancies became apparent for w 2 and w g .