This study aims to examine the effects of ambient pressure, fuel temperature, and ambient temperature on the macroscopic characteristics of a methanol low-pressure spray. Backlight imaging and high-speed photography are used to record spray morphology. The experimental conditions include the normal, transitional, and strong flash-boiling states. The flash-boiling state significantly increases the spray penetration and angle. The plumes of the strong flashboiling spray shrink along the injector axis into a long, narrow liquid beam, and the spray morphology is similar to that of a shuttle. The flash-boiling spray yields different performance at various ambient temperatures despite constant fuel superheat, which indicates that the flash-boiling state is affected by both the fuel superheat and ambient temperature. Moreover, the influence mechanism is examined. A high ambient temperature increases the likelihood and severity of bubble burst. By contrast, a low ambient temperature hinders bubble expansion and bursting, reducing the flash-boiling intensity. Furthermore, a dimensionless analysis of the non-flash-boiling spray velocity is performed, and the correlation between the non-flash-boiling spray velocity and air-fuel density ratio, Weber number, and Reynolds number is established. The deviation of the predictive value from the correlation and measured value is within ±5%. The results indicate that the Reynolds number has a less significant effect than the air-fuel density ratio and Weber number.