Planted forest plays a significant role in carbon sequestration and climate change mitigation; however, little information has been available on the distribution patterns of carbon pools with stand ages in Pinus massoniana Plantations. We investigated the biomass stock and carbon sequestration across a chronosequence (3-, 5-, 7-, 9-, 12-, 15-, 19-, 29-, 35-and 42-year) of stands with the main objectives: (1) to determine the biomass and carbon stock of the forest ecosystem; and (2) to identify factors influencing their distribution across the age series. Simple random sampling was used for collecting field data in the ten (10) stand ages. Three 20 × 20 m standard plots were laid out in February 2015 across the chronosequence. The diameter at breast height (DBH) and tree height (H) of each tree within each plot were measured using calipers and height indicator. Sub-plots of 2 × 2 m were established in each main plot for collecting soil samples at a 0-30-and 30-60-cm depth. Plantation biomass increased with increasing stand ages, ranging from 0.84 tonnes per hectare (t· ha −1 ) in the three-year stand to 252.35 t· ha −1 in the 42-year stand.The aboveground biomass (AGB) contributed 86.51%; the maximum value is 300-times the minimum value. Carbon concentrations and storage in mineral soil decreased with