INTRODUCTIONLead-tin solders have been used extensively as joining materials for the interconnection and packaging in modern electronic components and devices over the past several decades. However, alternatives for these solders are being sought due to environmental and economic issues. 1-4 One of the attractive leadfree solder candidates is tin-silver based solder because the reliability and mechanical properties are comparable to lead-tin solders. In high-temperature applications such as in automotive under-the-hood, aerospace, and military applications, eutectic tin-silver solder is appropriate due to its higher melting point. However, this solder may not be appropriate in some industrial applications due to cost concerns. It was found that adding third or fourth alloy elements to tin-silver solder can depress the melting temperature or improve some physical/mechanical properties. There have been several studies to investigate the effects of adding alloying elements in enhancing the performance of eutectic tin-silver solder. [5][6][7] Solder joints in service conditions experience internal thermal stresses due to coefficients of thermal expansion mismatches between the component leads, solder, and the substrate. The thermomechanical fatigue (TMF) will occur due to such thermal stresses that develop during temperature excursions encountered during service. As a result, mechanical deformation will occur in the solder joints. There have been studies of TMF on lead-tin solder during the last decade. 8-11 However, additional data are needed on the TMF of lead-free solders.Studies have clearly documented a significant amount of surface damage resulting from TMF in Sn-Ag based solder joints. 2,12 Based upon the evolution of damages such as intense shear banding, solder joint surface upheaval, grain boundary sliding, and decohesion and surface cracking, degradation of residual strength of the solder joints due to TMF should be expected. Thus, an investigation of residual-mechanical properties of solder joints in TMF is essential to evaluate their reliability in microelectronic applications. There have been few studies dealing with residual strength of lead-free solder joints that have experienced TMF. [13][14][15] reported that eutectic Sn-3.5Ag and Sn-Ag-0.5Cu solders showed better mechanical properties than eutectic Sn-37Pb after 1600 TMF cycles with temperature extremes between Ϫ30°C and 130°C in quad flat pack leads. Poon et al. 14 investigated the Thermomechanical fatigue (TMF) due to the mismatch in coefficients of thermal expansion between solder and substrate gradually degrades the mechanical properties of electronic solder joints during service. This study investigated the role of TMF on the residual-mechanical behavior of solder joints made with eutectic Sn-Ag solder and Sn-Ag solder with Cu or Ni additions. The TMF tests were carried out between Ϫ15°C and ϩ150°C with a ramp rate of 25°C/min for the heating segment and 7°C/min for the cooling segment. The hold times were 20 min at the high extreme and 300 m...