Materials engineering at the nanoscale by precise control of growth parameters can lead to many unusual and fascinating physical properties. The development of pulsed laser deposition (PLD) 25 years ago has enabled atomistic control of thin films and interfaces and as such it has contributed significantly to advances in fundamental material science. One application area is the research field of spintronics, which requires optimized nanomaterials for the generation and transport of spin-polarized carriers. The mixed valence manganite La 1-x Sr x MnO 3 (LSMO) is an interesting material for spintronics due to its intrinsic magnetoresistance properties, electric-field tunable metal-insulator transitions, and half-metallic band structure. Studies on LSMO thin-film growth by PLD show that the deposition temperature, oxygen pressure, laser fluence, strain due to substrate-film lattice mismatch, and post-deposition annealing greatly influence the magnetic and electrical transport properties of LSMO. For spintronic structures, robust ferromagnetic exchange interactions and metallic conductivity are desirable properties. In this article, we review the physics of LSMO thin films and the important role that PLD played to advance the field of LSMObased spintronics. Some specific application areas including magnetic tunnel junctions (MTJs), multiferroic tunnel junctions (MFTJs), and organic spintronic devices are highlighted, and the advantages, drawbacks, and opportunities of PLD-grown LSMO for next-generation spintronic devices are discussed.
IntroductionThe technology of spintronics uses the charge and spin of electrons to store information or to carry Pulsed laser deposition (PLD) [7] is a versatile thin-film deposition technique that can be used for nanoscale engineering of complex materials and interfaces. In correlated electron systems like LSMO, strong lattice-charge-spin coupling offers extensive control of magnetic and electronic transport properties by growth optimization and external actuation [8]. Besides intrinsic material parameters, spintronic elements often rely on band-structure effects at the interfaces between magnetic and non-magnetic thin films. Since the interface of LSMO is sensitive to bonding with other materials, charge transport due to polar discontinuities, and electric-field effects, it allows for the engineering of improved material responses and new functionalities. In this article, we review the use of PLD-grown LSMO films in spintronics. After an introduction to LSMO and a discussion on the control of LSMO properties using PLD, examples of LSMO