The degradation mechanism of solar cells is studied operando by electrical biasing in a TEM. • Tyukalova, E.; Duchamp, M. Atomic Resolution Enabled STEM Imaging of Nanocrystals at Cryogenic Temperature J. Phys. Mater. 2020, 3, 034006. 3 Demonstrates the implementation of cryogenic STEM to delay degradation caused by radiation damage.