1996
DOI: 10.1021/ic950965x
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Magnetic Properties of Cu2(OH)3(alkanecarboxylate) Compounds:  Drastic Modification with Extension of the Alkyl Chain

Abstract: Magnetic properties of the layered materials Cu 2 (OH) 3 (n-C m H 2m+1 COO) (m ) 0, 1, 7, 8, and 9) have been examined. X-ray powder diffraction patterns indicate that the interlayer distance increases in the order of m. The interlayer distances of the m ) 0 and 1 materials are shorter than the molecular heights of the intercalated carboxylates, respectively, while the distances of the m ) 7-9 materials are nearly double those of the molecular heights of the corresponding carboxylates, indicating a bilayer str… Show more

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Cited by 129 publications
(108 citation statements)
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“…The magnetic properties of intercalated copper hydroxides have been shown to exhibit a striking dependence on the interlayer spacing. [2][3][4] Hydroxy double salts, HDSs, are another more recently emerging class of compounds that hold similar promise for development as new nanostructured materials for a wide range of applications. HDSs, [(M 2+ 1 - x,Me 2+ 1+x)(OH)3(1 - y)] + A n-(1+3y)/n· zH2O, are similar to LDHs except that the metal hydroxide layer contains two divalent metals, designated here as M 2+ and Me 2+ .…”
Section: Introductionmentioning
confidence: 99%
“…The magnetic properties of intercalated copper hydroxides have been shown to exhibit a striking dependence on the interlayer spacing. [2][3][4] Hydroxy double salts, HDSs, are another more recently emerging class of compounds that hold similar promise for development as new nanostructured materials for a wide range of applications. HDSs, [(M 2+ 1 - x,Me 2+ 1+x)(OH)3(1 - y)] + A n-(1+3y)/n· zH2O, are similar to LDHs except that the metal hydroxide layer contains two divalent metals, designated here as M 2+ and Me 2+ .…”
Section: Introductionmentioning
confidence: 99%
“…The layered compounds M 2 (OH) 3 A (M = Co, Cu, and A = NO 3 -or OAc -) are shown to be well adapted for substitution reactions [9][10][11][12]. The exchange for large organic species (i.e.…”
Section: Introductionmentioning
confidence: 99%
“…The exchange for large organic species (i.e. aliphatic chain anions) coordinating the metal ion enables to tune the basal spacing, and accordingly to modify drastically the magnetic properties [11,12]. Thus, nalkyl chain molecules involving a single anionic function (carboxylate or sulfate anion), have been used to separate basic layers (Fig.…”
Section: Introductionmentioning
confidence: 99%
“…37) Another new anion exchangeable layered compound with a composition of Ni 1|x Zr 2x (OH) 2 (OCOCH 3 ) 2x« nH 2 O was pre pared by hydrothermal hydrolysis of NiZn mixed acetate solutions. 38) The structure is related to zinc basic salt, Zn 5 (OH) 8 Cl 2 EnH 2 O; as shown in Fig.…”
Section: )31)mentioning
confidence: 99%