2017
DOI: 10.1063/1.4978306
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Macroparticle generation in DC arc discharge from a WC cathode

Abstract: We have studied macroparticle generation from a tungsten carbide (WC) cathode used in a dc vacuum arc discharge. Despite a relatively high decomposition/melting point (~ 3100 K), there is an intensive generation of visible particles with sizes in the range 20-35 µm. Visual observations during the discharge and scanning electron microscopy of the cathode surface as well as of collected macroparticles indicate a new mechanism for particle formation and acceleration. Based on the W-C phase diagram there is an int… Show more

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Cited by 11 publications
(6 citation statements)
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“…Considering the high energy of thermal plasma and its intense interaction with the alloy composition, the design of the alloy system is application-specific for guaranteeing the desired erosion resistance over a sustained service period. Several reports have investigated the erosion characteristics of the binary alloy subjected to the arc discharge via different micro analyses [20,21]. To our knowledge, there are still only a few reports on the direct observation of the erosion behaviors of binary alloys during arc discharge, and the physical mechanism related to such phenomena has not yet been clarified.…”
Section: Introductionmentioning
confidence: 99%
“…Considering the high energy of thermal plasma and its intense interaction with the alloy composition, the design of the alloy system is application-specific for guaranteeing the desired erosion resistance over a sustained service period. Several reports have investigated the erosion characteristics of the binary alloy subjected to the arc discharge via different micro analyses [20,21]. To our knowledge, there are still only a few reports on the direct observation of the erosion behaviors of binary alloys during arc discharge, and the physical mechanism related to such phenomena has not yet been clarified.…”
Section: Introductionmentioning
confidence: 99%
“…The rough surfaces of those cathodes and the limited amount of Cu suggest that the generation of droplets from the spots may occur in a similar way as the proposed mechanism for a W-C cathode, see Ref. 5. This mechanism is based on the electrical explosion of thin necks attaching the cathode surface with protrusions.…”
Section: B Generation Of the Macroparticle Fluxmentioning
confidence: 66%
“…A widely used method for material synthesis in thin-film form is vacuum-arc evaporation, allowing the generation of metallic flux even when refractory elements are used as cathode materials. [4][5][6] The level of elemental mixing in the generated material flux, including both ions and neutral atoms, and in the resulting films is not attainable with the classic mixing methods. There are, however, still almost no reports on arc-plasma generation from Mo-Cu cathodes, even though arc evaporation is a common industrial process, and arc-deposited Mo-Cu layers are used in the automobile industry.…”
Section: Introductionmentioning
confidence: 99%
“…The practical outcomes of our findings include the ability to grow highly tetrahedral films of high hardness with lower macroparticle content, which would be a distinct advantage over other methods, such as the continuous and pulsed cathodic arc methods. This, combined with the reduced surface roughness arising from the smaller macroparticles present in the film (Figure 3c), allows the production of smoother ta-C films [41]. The ability to grow carbon films with high content of sp 2 hybridized carbon atoms, and particularly in multilayer configurations through simple process control, is also an advantage when higher electrical conductivity is desired such as for (Metal-Insulator-Metal) MIM films [42] or biosensors [43,44] or when the dry lubricant properties of a highly graphitic film are desired.…”
Section: J O U R N a L P R E -P R O O Fmentioning
confidence: 99%