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The processing power of high power Nd:YAG laser has been utilised to achieve the inherently high cooling rates required to form many of today's bulk metallic glasses (BMGs). The production of thick (≥250 m) amorphous surface layers has been considered. Microstructural and chemical observation techniques including scanning electron microscopy (SEM) and transmission electron microscopy (both with energy-dispersive X-ray spectrometry, EDS), and X-ray diffraction (XRD), reveal that fully amorphous layers are attainable. Coating-to-substrate adherence is functionally graded by virtue of an amorphous matrix interlayer around 50 m in depth. Actual cladding and remelting to Ti substrates indicate that the process of laser cladding is a suitable technique for the application of metallic glasses as surface layers. Hardness and nanoindentation profiles reveal hardnesses up to 13 GPa over the full depth of a coating, coupled with elastic modulus around 150 GPa, which are comparable with bulk metallic glass melt-spun ribbons. Tribological tests have also been conducted which reveal good wear properties are attainable and shear banding has been seen in the contact region. Scratch testing shows the layers may exhibit extremely low coefficients of friction, and again shear band formation is witnessed.

The single and multiple pulse laser ablation threshold of zinc and steel at picosecond laser pulse duration is studied as a function of initial surface roughness at laser wavelengths of 515 and 1030 nm. The initial surface topographies and the resulting crater morphologies are analyzed using confocal laser scanning microscopy (CLSM) and scanning electron microscopy (SEM). Reflectivity measurements of the initial surfaces show increased absorptivity with increasing surface roughness. It was found that the single pulse ablation threshold increases with increasing effective surface area; the latter resulting from surface roughness. Rougher surfaces tend to have a higher degree of incubation as well. From the experimental and simulation results, it appears that the absorbed energy contributes more to residual heat than to material ablation when effective surface area increases.

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An electron microscopy appraisal of tensile fracture in metallic glasses Matthews, D. T. A.; Ocelik, V.; Bronsveld, P. M.; De Hosson, J. Th. M. AbstractThree glass-forming alloy compositions were chosen for ribbon production and subsequent electron microscopy studies. In situ tensile testing with transmission electron microscopy (TEM), followed by ex situ TEM and ex situ scanning electron microscopy (SEM), allowed the deformation processes in tensile fracture of metallic glasses to be analysed. In situ shear band propagation was found to be jump-like, with the jump sites correlating with the formation of secondary shear bands. The effect of structural relaxation by in situ heating is also discussed. Nanocrystallization near the fracture surface was observed; however, no crystallization was also reported in the same sample and the reasons for this are discussed. Both the TEM and the SEM observations confirmed the presence of a liquid-like layer on or near the fracture surface of the ribbons. The formation of a liquid-like layer was characterized by the vein geometries and vein densities on the fracture surfaces and its dependence on shear displacement, d, is discussed. A simple model is adapted to relate the temperature rise during shear banding to the glass transition and melting temperatures and this is used to explain the variety of fracture surfaces which are developed for macroscopically identical tensile testing of metallic glasses together with features which exhibit local melting.

Hip-implants structured with anti-bacterial textures should show a low-friction coefficient and should not leach hazardous substances into the human body. The surface of a typical material used for hip-implants, namely Cobalt–Chrome–Molybdenum (CoCrMo) was textured with different types of laser-induced periodic surface structures (LIPSS)—i.e., low spatial frequency LIPSS (LSFL), hierarchical structures consisting of grooves superimposed with high spatial frequency LIPSS (HSFL) and Triangular shaped Nanopillars (TNP)—using a picosecond pulsed laser source. The effect of LIPSS on the wettability, friction, as well as wear of the structures, when slid against a polyethylene (PE) counter surface and biocompatibility was analyzed. Surfaces covered with LSFL show superhydrophobicity and grooves with superimposed HSFL, as well as TNP, show hydrophobic behavior. The coefficient of friction (CoF) of LIPSS against a polyethylene (PE) counter surface was found to be higher (ranging from 0.40 to 0.66) than the CoF of (polished) CoCrMo, which was found to equal 0.22. It was found that the samples release cobalt within biocompatible limits. Compared to polished reference surfaces, LIPSS cause higher friction of CoCrMo against PE contact. However, the wear of the PE counter surface only increased significantly for the LSFL textures. For these reasons, it is concluded that LIPSS are not suitable for a heavily loaded metal-on-plastic bearing contact.

Ablation of bulk polycrystalline zinc in air is performed with single and multiple picosecond laser pulses at a wavelength of 1030 nm. The relationships between the characteristics of the ablated craters and the processing parameters are analyzed. Morphological changes of the ablated craters are characterized by means of scanning electron microscopy and confocal laser scanning microscopy. Chemical compositions of both the treated and untreated surfaces are quantified with X-ray photoelectron spectroscopy. A comparative analysis on the determination of the ablation threshold using three methods, based on ablated diameter, depth and volume is presented along with associated incubation coefficients. The single pulse ablation threshold value is found to equal 0.21 J/cm. Using the calculated incubation coefficients, it is found that both the fluence threshold and energy penetration depth show lesser degree of incubation for multiple laser pulses.