2009
DOI: 10.1039/b802352m
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Luminescent metal–organic frameworks

Abstract: Metal-organic frameworks (MOFs) display a wide range of luminescent behaviors resulting from the multifaceted nature of their structure. In this critical review we discuss the origins of MOF luminosity, which include the linker, the coordinated metal ions, antenna effects, excimer and exciplex formation, and guest molecules. The literature describing these effects is comprehensively surveyed, including a categorization of each report according to the type of luminescence observed. Finally, we discuss potential… Show more

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Cited by 4,640 publications
(2,436 citation statements)
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References 134 publications
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“…In addition, luminescence can also be generated from guest chromophore or charge transfer between the host framework and guest molecules. The diversified luminescence mechanisms make MOFs a unique platform for various luminescence applications 2, 3, 4, 26, 27, 28, 29…”
Section: Introductionmentioning
confidence: 99%
“…In addition, luminescence can also be generated from guest chromophore or charge transfer between the host framework and guest molecules. The diversified luminescence mechanisms make MOFs a unique platform for various luminescence applications 2, 3, 4, 26, 27, 28, 29…”
Section: Introductionmentioning
confidence: 99%
“…1,2 Interest in these compounds has been motivated not only due to their interesting structures, but as a method to obtain solid materials with diverse applications in catalysis, 3 gas storage, magnetism, 4 and luminescence. 5 As a result, a variety of networks with interesting structures and topologies have been reported, and in particular, rigid organic ligands based upon N-donor ligands such as 4,4′-bipyridine (4,4′-bpy) have been heavily utilised, since they afford a high degree of control over the resulting coordination frameworks. Similarly, due to their more predictable coordination geometry, a large majority of research efforts in this area have focused on the use of d-block transition metal cations or clusters.…”
Section: Introductionmentioning
confidence: 99%
“…10,11 Furthermore, some guest molecules within MOFs can also emit and/or induce luminescence. 12 Currently, MOFs are considered as materials with great potential and with possible industrial applications such as, for example, luminescent materials, 13 sensors, 14 and photocatalysts. 15 With numerous unique properties, MOF-5, which was invented by Yaghi and co-workers 16 in 1999, has become one of the more promising MOFs.…”
Section: ■ Introductionmentioning
confidence: 99%