“…The crystal field splitting of Ce 3+ ions in chalcogenide hosts are expected to be stronger than those in oxide hosts, therefore, the absorption of the 4f-5d transitions may extend to the visible (400-500 nm) area. Hence, the Ce 3+ doped chalcogenide is a very appropriate phosphor excited by near-UV or blue-emitting diodes for solidstate lighting, such as CaS:Ce 3+ [17], Ca 10 (PO 4 ) 6 Y (Y = S, Se):Ce 3+ [18] and CaAl 2 S 4 :Sn 2+ , Ce 3+ [19] phosphors. The luminescence properties of SrLaGa 3 S 6 O:Eu 2+ and CaLaGa 3 S 6 O:Ce 3+ , Tb 3+ phosphors were first reported by our group, via replacing a portion of oxygen in (Sr, Ca)LaGa 3 O 7 by sulfur [20,21].…”