Abstract. The high uncertainty of calibration is the most serious factor limiting accurate measurements of the solar UV, needed for the assessment of global UV trends. In this study, the calibration of FEL-type standard lamps traceable to three primary standard laboratories were compared with a transfer uncertainty of _+ 1.4% (2o-). In comparison with the reference lamp, the spectral UV irradiance scales agreed within 1.5%. However, the difference between a new lamp and the present reference was 2%, which is close to the limits of total uncertainty. It was interesting to observe that one of the scales, based on a cryogenic absolute radiometer, was in good agreement with the scales based on blackbody radiation sources. , Examination of the long-term stability of the lamp-based UV scale in Finland showed a significant decrease of 6% in the scale when the standard lamp was changed to a lamp directly traceable to the primary standard of the National Institute of Standards and Technology (NIST). Previously, the lamp was traceable to the NIST through the secondary standard of Optronic Laboratories Inc. The main obstacle in improving the global conformity of UV scales is the instability of halogen standard lamps. On the basis of the present study, it is strongly recommended to use detector stabilization of the standard lamps and to investigate the use of portable detector standards in the intercomparisons between primary standards laboratories.
IntroductionThe increase of terrestrial UV at short wavelengths is associated with the decrease in stratospheric ozone. According to theoretical estimates, the increase in biologically effective UV during the last 20 years varies from a few percent at the equator to about 12% at high northern latitudes . Verifying the trends through measurements, however, is difficult because the accuracy of most solar UV measurements is not sufficient [Weatherhead et at., 1998]. For the best spectroradiometric systems the differences may be within _+5% [Gardiner and Kirsch, 1998], but differences up to ___20% are not uncommon. The accuracy problems are due to instrumental deficiencies, inadequate quality assurance of operators, and the uncertainty of calibration.Among the many instrumental error sources the most significant are the deviation of the angular response from the ideal cosine response (___2%), the nonideal slit function (_+1%), the instability of the wavelength scale (_+3%), and the calibration uncertainty (___2%).
Calibration Chains for Solar UV RadiometersThe commonly used methodology for the calibration of UV spectroradiometers is based on tungsten-halogen standard lamps calibrated by primary standards laboratories against 4821