Abstract. Most investigations on the nature and effects of solar ultraviolet (UV)radiation at the Earth's surface require measurements of high accuracy combined with well-defined procedures to assess their quality. Here we present a general evaluation of all relevant errors and uncertainties associated with measurements of spectral global irradiance in the UV. The uncertainties are quantified in terms of dependence of the characteristics of the spectroradiometer, the uncertainty of calibration standards, the solar zenith angle, and atmospheric conditions. The methodologies and equations presented can be applied to most spectroradiometers currently employed for UV research. The sources of error addressed include radiometric calibration, cosine error, spectral resolution, wavelength misalignment, stability, noise, stray light, and timing errors. The practical application of the method is demonstrated by setting up a complete uncertainty table for the mobile spectroradiometer of the Fraunhofer Institute for Atmospheric Environmental Research (IFU). This instrument has successfully participated in several international intercomparisons of UV spectroradiometers. The expanded uncertainty (coverage factor k -2) for measurements of global spectral irradiance conducted with this instrument varies between 6.3% in the UVA and 12.7% at 300 nm and 60 ø solar zenith angle. The expanded uncertainties in erythemally and DNA weighted irradiances are 6.1% and 6.6%, respectively. These expanded uncertainties are comparable to uncertainties at the 2or level in conventional statistics. A substantial reduction of these uncertainties would require smaller uncertainties in the irradiance standards used to calibrate the instrument. Though uncertainties caused by wavelength misalignment and noise become prominent in the shortwave UVB, which is the most important spectral range for UV trend detection, the results indicate that the accuracy of the IFU radiometer is sufficient to detect long-term trends in UV arising from a 3% change in atmospheric ozone. The detection of trends caused by a 1% change in ozone may be beyond the capabilities of current instrumentation.
Abstract. For the evaluation of radiative transfer models and for investigations on the influence of parameters like aerosols or clouds on ground level UV irradiance, a combination of spectral measurements and model calculations is required. We show an efficient method for such a combination and present a systematic comparison of the freely available UVSPEC radiative transfer model package with two years of spectrally resolved measurements made at Garmisch-Partenkirchen, Germany (47.48øN, 11.07øE, 730 m above sea level) for cloudless sky and low albedo. More than 1200 spectra have been used for the comparison, covering a wide range of ozone and aerosol conditions. Applying the PSEUDO-SPHERICAL model type, a discrete ordinate model with correction for the sphericity of the Earth, the systematic differences between measurement and model were found to range between-11 and +2% for wavelengths between 295 and 400 nm and solar zenith angles up to 80 ø . The small observed statistical differences of 2-3% can mostly be explained by the random error of the measurement system. Only two input parameters, total ozone column and aerosol optical depth, the latter parameterized by the J•ngstrSm formula, are required to reach this level of agreement. It was further found that knowledge of the aerosol optical depth is essential for obtaining such a good agreement. The evaluated UVSPEC model package, together with the presented interface $DMODEL, provides an eflqcient tool for the investigation of the processes that control surface UV irradiance.
Abstract. In this paper, we describe the PALM model system 6.0. PALM (formerly an abbreviation for Parallelized Large-eddy Simulation Model and now an independent name) is a Fortran-based code and has been applied for studying a variety of atmospheric and oceanic boundary layers for about 20 years. The model is optimized for use on massively parallel computer architectures. This is a follow-up paper to the PALM 4.0 model description in Maronga et al. (2015). During the last years, PALM has been significantly improved and now offers a variety of new components. In particular, much effort was made to enhance the model with components needed for applications in urban environments, like fully interactive land surface and radiation schemes, chemistry, and an indoor model. This paper serves as an overview paper of the PALM 6.0 model system and we describe its current model core. The individual components for urban applications, case studies, validation runs, and issues with suitable input data are presented and discussed in a series of companion papers in this special issue.
Abstract. The Network for the Detection of Atmospheric Composition Change (NDACC) is an international global network of more than 90 stations making high-quality measurements of atmospheric composition that began official operations in 1991 after 5 years of planning. Apart from sonde measurements, all measurements in the network are performed by ground-based remote-sensing techniques. Originally named the Network for the Detection of Stratospheric Change (NDSC), the name of the network was changed to NDACC in 2005 to better reflect the expanded scope of its measurements. The primary goal of NDACC is to establish long-term databases for detecting changes and trends in the chemical and physical state of the atmosphere (mesosphere, stratosphere, and troposphere) and to assess the coupling of such changes with climate and air quality. NDACC's origins, station locations, organizational structure, and data archiving are described. NDACC is structured around categories of ground-based observational techniques (sonde, lidar, microwave radiometers, Fourier-transform infrared, UV-visible DOAS (differential optical absorption spectroscopy)-type, and Dobson–Brewer spectrometers, as well as spectral UV radiometers), timely cross-cutting themes (ozone, water vapour, measurement strategies, cross-network data integration), satellite measurement systems, and theory and analyses. Participation in NDACC requires compliance with strict measurement and data protocols to ensure that the network data are of high and consistent quality. To widen its scope, NDACC has established formal collaborative agreements with eight other cooperating networks and Global Atmosphere Watch (GAW). A brief history is provided, major accomplishments of NDACC during its first 25 years of operation are reviewed, and a forward-looking perspective is presented.
Abstract. Results from an intercomparison campaign of ultraviolet spectroradiometers that was organized at Nea Michaniona, Greece July, 1-13 1997, are presented. Nineteen instrument systems from 15 different countries took part and provided spectra of global solar UV irradiance for two consecutive days from sunrise to sunset every half hour. No data exchange was allowed between participants in order to achieve absolutely independent results among the instruments. The data analysis procedure included the determination of wavelength shifts and the application of suitable corrections to the measured spectra, their standardization to common spectral resolution of 1 nm full width at half maximum and the application of cosine corrections. Reference spectra were calculated for each observational time, derived for a set of instruments which were objectively selected and used as comparison norms for the assessment of the relative agreement among the various instruments. With regard to the absolute irradiance measurements, the range of the deviations from the reference for all spectra was within ñ20%. About half of the instruments agreed to within ñ5%, while only three fell outside the ñ 10% agreement limit. As for the accuracy of the wavelength registration of the recorded spectra, for most of the spectroradiometers (14) the calculated wavelength shifts were smaller than 0.2 nm. The overall outcome of the campaign was very encouraging, as it was proven that the agreement among the majority of the instruments was good and comparable to the commonly accepted uncertainties of spectral UV measurements. In addition, many of the instruments provided consistent results relative to at least the previous two intercomparison campaigns, held in 1995 in Ispra, Italy and in 1993 in Garmisch-Partenkirchen, Germany. As a result of this series of intercomparison campaigns, several of the currently operating spectroradiometers operating may be regarded as a core group of instruments, which with the employment of proper operational procedures are capable of providing quality spectral solar UV measurements.
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