Temperature dependent surface photovoltage spectra of type I GaAs1−xSbx/GaAs multiple quantum well structures J. Appl. Phys. 113, 073702 (2013); 10.1063/1.4792065 Photoreflectance and surface photovoltage spectroscopy of beryllium-doped Ga As ∕ Al As multiple quantum wells J. Appl. Phys. 98, 023508 (2005); 10.1063/1.1978970 Temperature dependent photoreflectance and photoluminescence characterization of GaInNAs ∕ GaAs single quantum well structures J. Appl. Phys. 96, 6298 (2004); 10.1063/1.1805724Modeling and analysis of photomodulated reflectance and double crystal x-ray diffraction measurements of tensilely strained InGaAs/InGaAsP quantum well structuresWe present photoreflectance ͑PR͒ and surface photovoltage spectroscopy ͑SPS͒ studies of GaAs 1−x Sb x / GaAs multiple quantum well structures with fundamental transition close to 1.3 m. These two optical diagnostic tools are powerful supplementary techniques in the investigations of complicated quantum systems. PR gives detailed information about the heavy-holes related transitions, while SPS contains additional information concerning light-holes related ones. The comparison of experimental data and theoretical analysis based on the envelope function approximation, including strain and exciton binding energy, allows us to identify the observed PR and SPS features. The results point to the existence of weak type-I band alignment in samples being studied, and the Sb content dependent of conduction band offset is found to agree well with that reported by Wang et al. ͓Phys. Rev. B 70, 195339 ͑2004͔͒.