2008
DOI: 10.1007/s11664-008-0489-1
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Low-Temperature, Strong SiO2-SiO2 Covalent Wafer Bonding for III–V Compound Semiconductors-to-Silicon Photonic Integrated Circuits

Abstract: We report a low-temperature process for covalent bonding of thermal SiO 2 to plasma-enhanced chemical vapor deposited (PECVD) SiO 2 for Si-compound semiconductor integration. A record-thin interfacial oxide layer of 60 nm demonstrates sufficient capability for gas byproduct diffusion and absorption, leading to a high surface energy of 2.65 J/m 2 after a 2-h 300°C anneal. O 2 plasma treatment and surface chemistry optimization in dilute hydrofluoric (HF) solution and NH 4 OH vapor efficiently suppress the small… Show more

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Cited by 86 publications
(53 citation statements)
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“…Such integration allows creating integrated optical devices, which take the best of both worlds: III-V semiconductors for efficient light emission and amplification and silicon for its low loss and high index contrast waveguiding. In order to densely integrate the III-V semiconductor with the silicon waveguide circuits, mainly molecular wafer bonding and DVS-BCB adhesive bonding techniques [2][3][4] are used and are actively reported in state-of-the-art hybrid amplifiers [5,6] and lasers [7][8][9][10][11]. In these approaches, unstructured InP-based dies are bonded, epitaxial layers down, on an SOI waveguide circuit wafer, after which the InP growth substrate is removed and the III-V epitaxial film is processed.…”
Section: Introductionmentioning
confidence: 99%
“…Such integration allows creating integrated optical devices, which take the best of both worlds: III-V semiconductors for efficient light emission and amplification and silicon for its low loss and high index contrast waveguiding. In order to densely integrate the III-V semiconductor with the silicon waveguide circuits, mainly molecular wafer bonding and DVS-BCB adhesive bonding techniques [2][3][4] are used and are actively reported in state-of-the-art hybrid amplifiers [5,6] and lasers [7][8][9][10][11]. In these approaches, unstructured InP-based dies are bonded, epitaxial layers down, on an SOI waveguide circuit wafer, after which the InP growth substrate is removed and the III-V epitaxial film is processed.…”
Section: Introductionmentioning
confidence: 99%
“…[9][10] In our work, we employ an adhesive bonding process using DVS-BCB as adhesive bonding agent. This technique does not require an ultra-clean surface unlike direct bonding, where the bond is formed based on van der Waals attraction between the two wafer surfaces.…”
Section: Heterogeneous Integrationmentioning
confidence: 99%
“…This leads to a universal angular distribution of the flux at the surface. The appropriate average transmission coefficient in this case is of the form (5) so that the transmitted power per unit area is (6) Definition (5) is commonly used in the discussion of equilibrium blackbody radiation (see, e.g., [8] and Appendix I).…”
Section: Angular Average Of Power Transmissionmentioning
confidence: 99%
“…The refractive index of the interlayer is typically considerably lower than that of both semiconductors. It is usually expected that films with optical thickness smaller than the wavelength should not disturb the radiation transmission or waveguiding properties [6]. This is indeed true for interlayers of higher refractive index.…”
Section: Introductionmentioning
confidence: 98%