Low-temperature-sintered Ba 3 (VO 4 ) 2 -CaWO 4 composite ceramics were prepared by cofiring mixtures of pure-phase Ba 3 (VO 4 ) 2 and CaWO 4 . The thermo-mechanical analysis revealed that the CaWO 4 in the composite ceramic can significantly promote the densification process and lower the sintering temperature to *900°C. The X-ray diffraction results indicated that Ba 3 (VO 4 ) 2 and CaWO 4 phases coexist in the sintered ceramics, and no secondary phases can be detected in the composite, implying the good chemical compatibility between the two phases. The near-zero temperature coefficients of the resonant frequency (s f ) could be achieved by adjusting the relative content of the two phases owing to their opposite s f values. The composite ceramics with 60 wt% CaWO 4 sintered at 900°C exhibited desirable microwave dielectric properties of the quality factor Q 9 f * 37,000 GHz, dielectric constant e r * 12, and s f * -1.4 ppm/°C.