We report direct measurements of the valley susceptibility, the change of valley population in response to applied symmetry-breaking strain, in an AlAs two-dimensional electron system. As the two-dimensional density is reduced, the valley susceptibility dramatically increases relative to its band value, reflecting the system's strong electron-electron interaction. The increase has a remarkable resemblance to the enhancement of the spin susceptibility and establishes the analogy between the spin and valley degrees of freedom.PACS numbers: 71.70.Fk , 73.43.Qt Currently, there is considerable interest in controlled manipulation of electron spin in semiconductors. This interest partly stems from the technological potential of spintronics, namely, the use of carrier spin to realize novel electronic devices. More important, successful manipulation of spins could also impact the more exotic field of quantum computing since many of the current proposals envision spin as the quantum bit (qubit) of information [1,2,3]. Here we describe measurements of another property of electrons, namely their valley degree of freedom, in a semiconductor where they occupy multiple conduction band minima (valleys) [ Fig. 1(a)]. Specifically, for a two-valley, two-dimensional electron system (2DES) in an AlAs quantum well, we have determined the "valley susceptibility", χ v , i.e., how the valley populations respond to the application of symmetry-breaking strain. This is directly analogous to the spin susceptibility, χ s , which specifies how the spin populations respond to an applied magnetic field [Figs. 1(d)]. Our data show that χ v and χ s have strikingly similar behaviors, including an interaction-induced enhancement at low electron densities. The results establish the general analogy between the spin and valley degrees of freedom, implying the potential use of valleys in applications such as quantum computing. We also discuss the implications of our results for the controversial metal-insulator transition problem in 2D carrier systems.It is instructive to describe at the outset the expressions for the band values of spin and valley susceptibilities χ s,b and χ v,b [4]. The spin susceptibility is defined as χ s,b = d∆n/dB = g b µ B ρ/2, where ∆n is the net spin imbalance, B is the applied magnetic field, g b is the band Landé g-factor, and ρ is the density of states at the Fermi level. Inserting the expression ρ = m b /πh 2 for 2D electrons, we have χ s,b = (µ B /2πh 2 )g b m b , where m b is the band effective mass. In analogy to spin, we can define valley susceptibility as χ v,b = d∆n/dǫ = ρE 2,b = (1/πh 2 )m b E 2,b , where ∆n is the difference between the populations of the majority and minority valleys, ǫ is strain, and E 2,b is the conduction band deformation potential [5]. In a Fermi liquid picture, the interparticle interaction results in replacement of the parameters m b , g b , and E 2,b [6] by their normalized values m * , g * , and E * 2 . Note that χ s ∝ m * g * and χ v ∝ m * E * 2 . Our experiments were performed on...