SWNT synthesis, 13 atomic layer deposition (ALD) of HfO 2 10,14,15 (t ox =8nm) and details of device fabrication are similar to those described previously. In Fig.1, we first show the electrical properties of a back-gated (t SiO2 =10nm, Fig. 1a) semiconducting SWNT (d~1.4 to 1.5 nm, channel length L~150 nm between Pd source/drain S/D) device before and after K-doping (details of doping described previously [16][17][18] ). The as-made device is a p-type FET with I on~ 5µA and linear conductance of G on~0 .3 e 2 /h (Fig. 1b). technique. 10,14,15 The nanotube segments outside the gate stack are fully exposed for K vapor doping to form n + regions (Fig.2a). ALD of HfO 2 on SWNTs provides excellent electrostatic modulation of the channel conductance without degrading the transport property of the 1D nanotube channels. 3,9,10 This is another key element in affording high performance n-type SWNT FETs.Prior to K doping, the devices operated as p-MOSFETs (Fig. 2b blue curve) when the two ends of the tube were electrostatically hole-doped by a back-gate. 21 Upon exposure to K vapor in vacuum, the S/D regions became n-doped while the top-gated channel regions remained intrinsic due to blocking of K by the gate stack. This afforded n + -i-n + n-type nanotube MOSFETs. The electrical properties of a SWNT (d~1.6-1.7 nm; E g ~0.55eV) MOSFET before (p-type) and after K-doping (n-type) in vacuum are shown showed near-symmetrical characteristics with similar on-currents I on~ 8 µA at V ds =0.5 (Fig. 2c). The transconductance were (dI ds /dV gs ) max ~ 20 µS and ~10 µS for n-and pFETs respectively. Both devices exhibited excellent switching characteristics with subthreshold swings S=dI ds /dV gs~7 0-80 mV/decade (Fig. 2b), near the theoretical limit of S~60 mV/decade. Note that at V ds =0.5V, a high I on /I off ~10 6 was achieved for the nanotube n-MOSFET with no significant ambipolar p-channel conduction (Fig. 2b red curve). These characteristics are the best reported to-date for n-type nanotube FETs enabled by the MOSFET geometry 6,22 with chemically doped S/D, high-κ dielectrics and transparent metal-tube contacts. In such a MOSFET-like geometry the gate electric fields result in bulk switching of the nanotube directly under the gate-stack with little effect to the Schottky barriers at the metal-tube junctions.We next investigated the effects of the contacts doping level on the electrical characteristics of our nanotube n-FETs. The doping level was varied by adjusting the exposure time of the devices to K atoms. Fig. 3a (dashed curve) shows the switching properties for the same device in Fig.2 but at a higher degree of n-doping of the S/D contacts. The on-current of the device increased from ~ 8µA to 15 µA at V ds =0.5 V (Fig. 3b), attributed to further enhanced transparency at the Pd-tube junctions and lower series resistance in the n + nanotube segments. The on-current increase was, however, accompanied by a more obvious ambipolar p-channel conduction, an increase in the minimum leakage current (I min ) and a reduction of I ...