The reflected 0th and −1st diffraction orders of a waveguide grating can be switched between 0 and 1 diffraction efficiency upon the excitation of a forward- and backward-propagating waveguide mode by means of the +1st and −2nd orders. Such mode-coupling trigger of high isolation switching is found to be in the neighborhood of the −1st order Littrow condition under the condition that no transmitted order can propagate; the condition is here fulfilled without loss penalty by reflecting them under total internal reflection. This requires a waveguide refractive index larger than 3, and resorting to a semiconductor in the near infrared. This non-Fano phenomenon is yet another feature of resonant gratings. The reflective switching effect lends itself to a stable monolithic implementation, and can be used for wavelength control, or for the evanescent wave sensing of measurands in the transmission medium.