Low-cost superior solid-state symmetric supercapacitors based on hematite nanocrystals

Abstract

We present a facile method for the fabrication of hematite nanocrystal-carbon cloth (FeO-CC) composite. Hierarchical manganite is chosen as the sacrificial precursor, that does not contribute to the component of final iron oxide but can be in situ dissolved by the acid produced from the Fe hydrolysis. This method effectively enhances the specific surface area and conductivity of hematite (FeO) by attaching FeO nanocrystals (around 5 nm) firmly on the surface of carbon fibers. The obtained FeO-CC can be directly used as a binder-free electrode for a supercapacitor. Interestingly, the composite electrode exhibits synergistic electrochemical capacitance (electrochemical double-layer capacitance and pseudo-capacitance). It manifests a very high areal capacitance of 1.66 F cm (1660 F g) at 2 mA cm and excellent cycling performance at large current densities (88.6% retention at 30 mA cm after 5000 cycles) in a three-electrode testing system, which is among the best performances reported in the literature. Importantly, when fabricated as a solid-state flexible symmetric supercapacitor it still shows a maximum energy density of 8.74 mW h cm and power density of 253.9 mW cm. Additionally, its good flexibility makes it suitable for portable devices.

Iron oxide-based nanomaterials for supercapacitors

“…In addition, the obtained ASC showed a high energy density of 12.4 W h kg −1 at 951 W kg −1 and a good cycle performance with 85% retention after 1 0000 charge-discharge cycles. A flexible-solid-state symmetric supercapacitor (FSS-SSC) based on hematite nanocrystal-CC (Fe 2 O 3 −CC) composite electrodes was fabricated by Peng et al [111]. As shown in figure 9(a), first, a layer of hierarchical manganite was introduced on the CC.…”