“…However, under the acid conditions in gastric fluid, arsenic released from soluble phases like calcium arsenate or arseniosiderite could adsorb to co-occurring, sparingly-soluble ferric hydroxides thus attenuating the measured bioaccessible fraction. 85,86 At the acid pH of SGF (1.5), precipitation of ferrihydrite was not thermodynamically favorable (PM 150 log Ω 100 h-SGF = −2.2), although there was a thermodynamic drive for akaganeite and plumbojarosite (PM 150 log Ω 100 h = 11.3) precipitation. The pre-existence of jarosite surfaces could serve as a template to decrease the activation energy (degree of supersaturation) required for nucleation and crystal growth, 87,88 which could sequester both arsenate and lead during long term low pH SGF IVBA exposure.…”